In situ Raman spectroscopic study towards the growth and excellent HER catalysis of Ni/Ni(OH)2 heterostructure

The electrochemical water splitting to produce H-2 in high efficiency with earth-abundant metal catalysts remains a challenge. Here, we describe a simple "cyclic voltammetry thorn ageing" protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)(2) heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)(2) heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)(2) amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni-Ni(OH)(2) interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H-2-evolving current density of 10 mA/cm(2) and 153 mV at 100 mA/cm(2), as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)(2) heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni-Ni(OH)(2) interface reducing the energy barrier of H* adsorption thus promoting the HER performance. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.