Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)2(py)2]

被引：0
作者：
Seddigi, Zaki S.
Banu, Afroza
Hossain, G. M. Golzar
机构：
[1] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia
[2] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
来源：
ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING | 2007年 / 32卷 / 2A期
关键词：
crystal structure; saccharinate; pyridine;
D O I：
暂无
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The structure of the mercury saccharinate complex with pyridine has been studied by IR and single crystal X-ray diffraction methods. The compound was,crystallized in the monoclinic space group P2(1)/n with unit cell dimensions of a = 9.8114(2) b = 21.2444(3), c = 12.0557(5), 8 = 97.8431(8)degrees, Z = 4, and the crystal structure was solved to an R value of 0.0425 for 5700 observations. The Hg atom has slightly distorted tetrahedral configuration with four nitrogen (N) atoms from two pyridine and two saccharinate anions in the complex.
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页码：181 / 187
页数：7
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