Multiphoton mass spectra of XeKr molecules in the range of excited Xe*6p[5/2]2,3 atoms

被引:8
作者
Khodorkovskii, M. A. [1 ]
Belyaeva, A. A.
Rakeheeva, L. P.
Pastor, A. A.
Serdobintsev, P. Yu.
Timofeev, N. A.
Shevkunov, I. A.
Hallin, R.
Siegbahn, K.
机构
[1] Russian Sci Ctr Appl Chem, St Petersburg 197198, Russia
[2] St Petersburg State Univ, St Petersburg 198904, Russia
[3] Uppsala Univ, Fys Inst, SE-751 Uppsala, Sweden
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/S0030400X07060069
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Data on excited states of XeKr molecules in the energy range 78280-77600 cm(-1) are obtained. Using the method of multiphoton laser photoionization of molecules in a supersonic jet, five vibrational progressions of XeKr molecules are obtained, which are attributed to five electronic-vibrational transitions from the ground state of the XeKr molecule of the symmetry 0(+) to excited states of the symmetry Omega = 0(+), 1, 2 with the dissociation limit (KrS0)-S-1 + Xe*6p[5/2](2) and of the symmetry Omega = 1, 2 with the dissociation limit Kr + Xe*6p[5/2](3). The molecular constants of the corresponding excited states of the XeKr molecule are estimated.
引用
收藏
页码:834 / 841
页数:8
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