Crystal structure of N,N′-bis-thiophene-2-yl-methylene-propane-1,3-diamine

被引:0
|
作者
Naskar, Jnan Prakash [1 ]
Guhathakurta, Bhargab [1 ]
Bhattacharya, Rahul [2 ]
Zhu, Miaoli [3 ]
Lu, Liping [3 ]
机构
[1] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, India
[2] Indian Chem Soc, 92 Acharya Prafulla Chandra Rd, Kolkata 700009, India
[3] Shanxi Univ, Engn Educ Minist, Key Lab Chem Biol & Mol, Inst Mol Sci, 92 Wucheng Rd, Taiyuan 030006, Shanxi, Peoples R China
关键词
Schiff base; bidentate ligand; X-ray crystal structure; SCHIFFS BASE; COPPER;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, N,N'-bis-thiophene-2-yl-methylene-propane-1,3-diamine (1), C13H14N2S2 was synthesized in dry methanol. On crystallization from the methanolic mother liquor, single crystals suitable for X-ray diffraction of 1 were harvested. The compound crystallizes in the monoclinic crystal system with P-2(1)/c, space group having a = 8.4379(2), b = 16.5735(4), c = 10.6494(3) angstrom, beta = 115.703(2), V = 1341.91(6) angstrom(3) and Z = 4. This compound is a potential bidentate ligand with two nitrogens only as donor centres as evidenced from all the crystal structures hitherto reported on this type of systems.
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页码:49 / 53
页数:5
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