The Chemical Bond: The Perspective of NMR Spectroscopy

被引:26
作者
Dracinsky, M. [1 ]
机构
[1] Acad Sci, Inst Organ Chem & Biochem, Prague, Czech Republic
来源
ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 90 | 2017年 / 90卷
关键词
NMR spectroscopy; Chemical bonding; Bond distance; Chemical shifts; DFT calculations; Hydrogen bonding; SOLID-STATE NMR; NUCLEAR-MAGNETIC-RESONANCE; CROSS-CORRELATED RELAXATION; CENTER-DOT-O; INTRAMOLECULAR HYDROGEN-BONDS; RESIDUAL DIPOLAR COUPLINGS; SHIFT ANISOTROPY TENSORS; AB-INITIO CALCULATIONS; SPIN-SPIN COUPLINGS; ACID-BASE COMPLEXES;
D O I
10.1016/bs.arnmr.2016.07.001
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
This review article deals with chemical bonding from the perspective of nuclear magnetic resonance (NMR) spectroscopy. Different types of chemical bonds are briefly discussed and the relation between chemical bonding and NMR observables is overviewed. The various NMR interactions are classified in terms of through-bond and through-space effects on their observable values. The effects of vibrational motion and nuclear delocalization on NMR parameters and the consequences for the experimental determination of bond distances are also discussed. Finally, NMR experiments in studies of hydrogen bonding are summarized in Section 5.
引用
收藏
页码:1 / 40
页数:40
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