Unprecedented tunable hydrophobic effect and anion recognition triggered by AIE with Hofmeister series in water

被引:14
作者
Wang, Pan [1 ]
Cao, Shixian [1 ]
Yin, Ting [1 ]
Ni, Xin-Long [1 ]
机构
[1] Guizhou Univ, Key Lab Macrocycl & Supramol Chem Guizhou Prov, Guiyang 550025, Peoples R China
基金
中国国家自然科学基金;
关键词
AIE; Anion binding; Hofmeister series; Hydrophobic effect; Self-assembly; AGGREGATION-INDUCED EMISSION; IONS; POLYMER;
D O I
10.1016/j.cclet.2020.11.068
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An unprecedented tunable hydrophobic effect in self-assembly of a small cationic organic fluorophore (NI-TPy+)-based with aggregation-induced emission (ALE) property was realized in aqueous solution. The amplification of hydrophobicity was found to be significantly dependent upon the increasing aggregates of NI-TPy+, which enabled the study of the hydrophobic binding of chaotropic anions with the Hofmeister series. (C) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1679 / 1682
页数:4
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