Magnetic Nanocomposites: A New Perspective in Catalysis

被引:443
作者
Zhu, Yinghuai [1 ]
Stubbs, Ludger Paul [1 ]
Ho, Feny [1 ]
Liu, Rongzhen [1 ]
Ship, Chee Peng [2 ]
Maguire, John A. [3 ]
Hosmane, Narayan S. [4 ]
机构
[1] Inst Chem & Engn Sci, Singapore 627833, Singapore
[2] Natl Univ Singapore, Dept Chem, Singapore 177543, Singapore
[3] So Methodist Univ, Dept Chem, Dallas, TX 75275 USA
[4] No Illinois Univ, Dept Chem & Chem Biol, De Kalb, IL 60115 USA
基金
美国国家科学基金会;
关键词
heterogeneous catalysis; homogeneous catalysis; immobilization; magnetic properties; nanoparticles; IRON-OXIDE NANOPARTICLES; RUTHENIUM-CARBENE COMPLEX; SUPERPARAMAGNETIC NANOPARTICLES; ASYMMETRIC HYDROGENATION; POLY(ETHYLENE GLYCOL); SURFACE MODIFICATION; CONTRAST AGENTS; BY-PRODUCTS; PALLADIUM; SUZUKI;
D O I
10.1002/cctc.200900314
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, the synthesis and applications of magnetic nanoparticles (MNPs) have attracted increasing interest in catalysis research, and MNP-derived catalysts have been employed in such industrially important reactions as hydrogenation, hydroformylation, Suzuki-Miyaura and Heck couplings, and olefin metathesis. The hybrid nanocomposite species display sustainable catalytic activities and great advantages concerning catalyst recycling processes. A number of examples using these innovative hybrids in catalysis have been reported with promising results. This Minireview primarily addresses recent catalytic applications of magnetic nanocomposites, including a discussion of the synthetic methodologies that are commonly used.
引用
收藏
页码:365 / 374
页数:10
相关论文
共 142 条
[1]   Metal supported on dendronized magnetic nanoparticles: Highly selective hydroformylation catalysts [J].
Abu-Reziq, R ;
Alper, H ;
Wang, DS ;
Post, ML .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (15) :5279-5282
[2]   Platinum nanoparticles supported on ionic liquid-modified magnetic nanoparticles: Selective hydrogenation catalysts [J].
Abu-Reziq, Raed ;
Wang, Dashan ;
Post, Michael ;
Alper, Howard .
ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (13) :2145-2150
[3]   Preparation of a biocompatible magnetic film from an aqueous ferrofluid [J].
Albornoz, Cecilia ;
Jacobo, Silvia E. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2006, 305 (01) :12-15
[4]   Synthesis based on the wet impregnation method and characterization of iron and iron oxide-silica nanocomposites [J].
Alcala, M. D. ;
Real, C. .
SOLID STATE IONICS, 2006, 177 (9-10) :955-960
[5]  
Alvarez G.S., 2006, CHEM ENG SCI, V61, P4625
[6]  
ANNA M, 2006, CHEM COMMUN, P841
[7]  
ARMANDO B, 1992, APPL CATAL A-GEN, V80, P115
[8]   Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].
Astruc, D ;
Lu, F ;
Aranzaes, JR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872
[9]  
Astruc D., 2005, Angew. Chem, V117, P8062, DOI DOI 10.1002/ange.200500766
[10]   Synthesis of iron oxide nanoparticles used as MRI contrast agents: A parametric study [J].
Babes, L ;
Denizot, B ;
Tanguy, G ;
Le Jeune, JJ ;
Jallet, P .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 212 (02) :474-482