Fisher information and density functional theory

被引:13
作者
Nagy, Agnes [1 ]
机构
[1] Univ Debrecen, Dept Theoret Phys, H-4002 Debrecen, Hungary
关键词
Coulomb systems; density functional theory; Fisher information; KINETIC-ENERGY DENSITY; PHASE-SPACE APPROACH; SHANNON-INFORMATION; ELECTRON-DENSITY; GROUND-STATE; EXCITED-STATES; RENYI ENTROPY; WAVE-VECTOR; SQUARE-ROOT; PRINCIPLE;
D O I
10.1002/qua.26679
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Relationship of Fisher information and density functional theory is reviewed. Links between the Fisher and Shannon information, the local wave-vector and the relative information are displayed. Euler equations for the Fisher and relative Fisher information are presented. A combined information theoretical and thermodynamic view of density functional theory is analyzed. The extremum of the Shannon and Fisher information results a constant temperature and for Coulomb systems a simple relation between the total energy and phase-space Fisher information. Relations for phase-spase fidelity, fidelity susceptibility and relative information are also presented.
引用
收藏
页数:18
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