Carbonium ions.

被引:3
作者
Mota, CJA [1 ]
机构
[1] Univ Fed Rio de Janeiro, Dept Quim Organ, Inst Quim, BR-21949900 Rio De Janeiro, Brazil
来源
QUIMICA NOVA | 2000年 / 23卷 / 03期
关键词
carbonium ions; alkane protonation; three center two electron bond;
D O I
10.1590/S0100-40422000000300011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbonium ions are carbocations with a pentacoordinated carbon atom, where the electronic octet is maintained. They possess a three center two electron bond in order to keep the tetravalence of the carbon atom. This paper reviews the concept of carbonium ions, their formation, stability and reactions.
引用
收藏
页码:338 / 345
页数:8
相关论文
共 100 条
[21]  
Commeyras A., 1969, J AM CHEM SOC, V91, P2929
[22]   PROXIMITY EFFECTS .21. ESTABLISHMENT OF 1,3-HYDRIDE AND 1,5-HYDRIDE SHIFTS IN THE SOLVOLYSIS OF CIS-CYCLOOCTENE OXIDE [J].
COPE, AC ;
BERCHTOLD, GA ;
PETERSON, PE ;
SHARMAN, SH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) :6366-6369
[23]  
CORMA A, 1989, ZEOLITES FACTS FIGUR, P49
[24]   THE 3-CENTER, 2-ELECTRON CHEMICAL-BOND [J].
DEKOCK, RL ;
BOSMA, WB .
JOURNAL OF CHEMICAL EDUCATION, 1988, 65 (03) :194-197
[25]   Near Hartree-Fock energy and equilibrium geometry of CH5+ [J].
Dyczmons, V. ;
Staemmler, V. ;
Kutzelnigg, W. .
CHEMICAL PHYSICS LETTERS, 1970, 5 (06) :361-366
[26]   Potential energy surface of the C3H9+ cations.: Protonated propane [J].
Esteves, PM ;
Mota, CJA ;
Ramírez-Solís, A ;
Hernández-Lamoneda, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (13) :3213-3219
[27]   Mechanism of superacid catalyzed alkane activation: theoretical ab initio studies of pentacoordinated carbonium ion rearrangement [J].
Esteves, PM ;
Mota, CJA ;
Ramirez-Solis, A ;
Hernandez-Lamoneda, R .
TOPICS IN CATALYSIS, 1998, 6 (1-4) :163-168
[28]   The alkane σ-bond basicity scale revisited [J].
Esteves, PM ;
Alberto, GGP ;
Ramírez-Solís, A ;
Mota, CJA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7345-7348
[29]   REVERSIBLE REACTIONS OF GASEOUS IONS .3. STUDIES WITH METHANE AT 0.1-1.0 TOR AND 77-300 DEGREES K [J].
FIELD, FH ;
BEGGS, DP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) :1585-&
[30]   PYROLYSIS OF C2H7+ AND OTHER ION-MOLECULE REACTIONS IN METHANE CONTAINING TRACES OF ETHANE [J].
FRENCH, M ;
KEBARLE, P .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (15) :2268-2274