A review on green Lewis acids: zirconium(IV) oxydichloride octahydrate (ZrOCl2•8H2O) and zirconium(IV) tetrachloride (ZrCl4) in organic chemistry

被引：66

作者：

Nikoofar, Kobra ^{[1
]}

Khademi, Zahra ^{[1
]}

机构：

[1] Alzahra Univ, Fac Phys & Chem, Dept Chem, Tehran, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2016年 / 42卷 / 05期

关键词：

ZrCl4; ZrOCl2 center dot 8H(2)O; Lewis acid catalyst; Multi-component reactions; Solvent-free; Organic transformations; ONE-POT SYNTHESIS; MICROWAVE-ASSISTED SYNTHESIS; SOLVENT-FREE SYNTHESIS; MANNICH-TYPE REACTION; BETA-AMINO KETONES; EFFICIENT CATALYST; HIGHLY EFFICIENT; ZIRCONYL CHLORIDE; CARBOXYLIC-ACIDS; EXPEDITIOUS SYNTHESIS;

D O I：

10.1007/s11164-015-2260-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lewis acids are important and interesting catalysts in most organic transformations. Among different Lewis acids, Zr(IV) species such as ZrCl4 and ZrOCl2 center dot 8H(2)O are allocated special attention because of their low toxicity, availability and handling, moisture stability, and low cost in comparison to some of their corresponding compounds. During recent decades, Lewis acids have been used to promote different types of organic reactions because they naturally possess mild acidity properties and, as such, can catalyze reactions selectively. This means that in the presence of various functional groups, they can operate on a specific group to produce the objective product. In this review we have focused on the reactions which have been progressed in the presence of ZrCl4 and ZrOCl2 center dot 8H(2)O. The study has been ordered based on the number of the reaction components and their solvent media.

引用

页码：3929 / 3977

页数：49

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