Bis(μ-N-methyl-N-phenyldithiocarbamato)-[bis(N-methyl-N-phenyldithiocarbamato)zinc(II)]

被引：10

作者：

Baba, I ^{[1
]}

Lee, LH

Farina, Y

Othman, AH

Ibrahim, AR

Usman, A

Fun, HK

Ng, SW

机构：

[1] Univ Kebangsaan Malaysia, Sch Chem Sci, Bangi 43600, Malaysia

[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536802021141

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Zn atom in the centrosymmetric title compound, [Zn-2 (C8H8NS2)(4)], is almost symmetrically coordinated by one terminal bidentate N-phenyl-N-methyldithiocarbamate ligand [Zn-S 2.348 (1) and 2.459 (1) Angstrom] and non-symmetrically coordinated by a second bidentate bridging dithiocarbamate ligand [Zn-S 2.316 (1) and 2.980 (1) Angstrom]. The latter also uses its bridging S atom to coordinate the second Zn atom [Zn-S 2.378 (1) Angstrom], thus forming a dimeric binuclear complex. Taking into account the long Zn...S distance, the Zn atom has a distorted trigonal-bipyramidal coordination.

引用

页码：M744 / M745

页数：2

共 7 条

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