Hydrothermal synthesis of blue-emitting silicon quantum dots for fluorescent detection of hypochlorite in tap water

被引:31
作者
Guo, Yongming [1 ]
Zhang, Lianfeng [1 ]
Cao, Fengpu [1 ]
Mang, Lianghong [1 ]
Lei, Xiaoling [1 ]
Cheng, Shengjuan [1 ]
Song, Jintong [1 ]
机构
[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
基金
中国国家自然科学基金;
关键词
LABEL-FREE; SENSITIVE DETECTION; FREE CHLORINE; CARBON DOTS; OXIDATIVE STRESS; REACTIVE OXYGEN; SYNOVIAL-FLUID; NANOPARTICLES; PROBE; MYELOPEROXIDASE;
D O I
10.1039/c5ay03325j
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A facile, sensitive and selective method for the fluorescent detection of hypochlorite in tap water has been developed by utilization of blue-emissive silicon quantum dots (SiQDs) with a quantum yield of 10.6%. The SiQDs are prepared via a simple hydrothermal treatment of (3-aminopropyl) trimethoxysilane and sodium citrate, and they display excellent stability in high salt conditions. The proposed preparation method for SiQDs does not require complicated synthesis and does not need the protection of an inert gas. It is attractive that the as-prepared SiQDs can be utilized to detect hypochlorite in tap water with relatively good selectivity and sensitivity, and as low as 0.01 mu M hypochlorite could be successfully determined.
引用
收藏
页码:2723 / 2728
页数:6
相关论文
共 51 条
[1]   DIRECT AND SEQUENTIAL POTENTIOMETRIC DETERMINATION OF HYPOCHLORITE, CHLORITE, AND CHLORATE IONS WHEN HYPOCHLORITE ION IS PRESENT IN LARGE EXCESS [J].
ADAM, LC ;
GORDON, G .
ANALYTICAL CHEMISTRY, 1995, 67 (03) :535-540
[2]  
American Public Health Association American Water Works Association and Water Pollution Control Federation, 1985, STANDARD METHODS EXA, P309
[3]   CONTINUOUS-FLOW DETERMINATION OF FREE CHLORINE IN WATER [J].
AOKI, T ;
MUNEMORI, M .
ANALYTICAL CHEMISTRY, 1983, 55 (02) :209-212
[4]   Luminescent probes for the bioimaging of small anionic species in vitro and in vivo [J].
Ashton, Trent D. ;
Jolliffe, Katrina A. ;
Pfeffer, Frederick M. .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (14) :4547-4595
[5]   A highly sensitive fluorescence assay for 2,4,6-trinitrotoluene using amine-capped silicon quantum dots as a probe [J].
Ban, Rui ;
Zheng, Fenfen ;
Zhang, Jianrong .
ANALYTICAL METHODS, 2015, 7 (05) :1732-1737
[6]   FRET spectral unmixing: a ratiometric fluorescent nanoprobe for hypochlorite [J].
Chen, Gengwen ;
Song, Fengling ;
Wang, Jingyun ;
Yang, Zhigang ;
Sun, Shiguo ;
Fan, Jiangli ;
Qiang, Xinxin ;
Wang, Xu ;
Dou, Bairui ;
Peng, Xiaojun .
CHEMICAL COMMUNICATIONS, 2012, 48 (24) :2949-2951
[7]   A highly specific ferrocene-based fluorescent probe for hypochlorous acid and its application to cell imaging [J].
Chen, Suming ;
Lu, Jinxin ;
Sun, Chengdong ;
Ma, Huimin .
ANALYST, 2010, 135 (03) :577-582
[8]   Colloidal silicon quantum dots: from preparation to the modification of self-assembled monolayers (SAMs) for bio-applications [J].
Cheng, Xiaoyu ;
Lowe, Stuart B. ;
Reece, Peter J. ;
Gooding, J. Justin .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (08) :2680-2700
[9]   A carbon dot-based hybrid fluorescent sensor for detecting free chlorine in water medium [J].
Ding, Yanjun ;
Ling, Jiang ;
Cai, Jifeng ;
Wang, Suiping ;
Li, Xingmei ;
Yang, Minghui ;
Zha, Lagabaiyla ;
Yan, Jie .
ANALYTICAL METHODS, 2016, 8 (05) :1157-1161
[10]   Disinfection efficacy of organic chloramines [J].
Donnermair, MM ;
Blatchley, ER .
WATER RESEARCH, 2003, 37 (07) :1557-1570