Multiferroic, Optical, and Fatigue Behavior of BiFeO3 Thin Films with a Sintering Aid of CuO

被引:3
作者
Wu, Jiagang [1 ]
Wang, John [1 ]
机构
[1] Natl Univ Singapore, Fac Engn, Dept Mat Sci & Engn, Singapore 117574, Singapore
关键词
bismuth compounds; copper compounds; dielectric polarisation; energy gap; fatigue; ferroelectric Curie temperature; ferroelectric thin films; multiferroics; sintering; sputter deposition; texture;
D O I
10.1149/1.3443221
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The BiFeO3 (BFO) thin film was doped with CuO (1 mol %), leading to the (100) orientation when deposited on SrRuO3/LaAlO3(100) substrate by off-axis radio-frequency magnetic sputtering. The CuO-doped BFO thin film retains a high Curie temperature (similar to 820 degrees C) and possesses a direct bandgap (2.75 eV). A giant remnant polarization of 2P(r) similar to 184.7 mu C/cm(2) and good fatigue endurance are also shown for the CuO-doped BFO thin film. Its frequency dependence of fatigue endurance was correlated with the impedance analysis, confirming the involvement of oxygen vacancies. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3443221] All rights reserved.
引用
收藏
页码:G68 / G70
页数:3
相关论文
共 17 条
[1]   Investigation on the origin of the magnetic moment of BiFeO3 thin films by advanced X-ray characterizations [J].
Bea, Helene ;
Bibes, Manuel ;
Fusil, Stephane ;
Bouzehouane, Karim ;
Jacquet, Eric ;
Rode, Karsten ;
Bencok, Peter ;
Barthelemy, Agnes .
PHYSICAL REVIEW B, 2006, 74 (02)
[2]   Multiferroic and magnetoelectric materials [J].
Eerenstein, W. ;
Mathur, N. D. ;
Scott, J. F. .
NATURE, 2006, 442 (7104) :759-765
[3]   Epitaxially grown la-modified BiFeO3 magnetoferroelectric thin films -: art. no. 222903 [J].
Lee, D ;
Kim, MG ;
Ryu, S ;
Jang, HM ;
Lee, SG .
APPLIED PHYSICS LETTERS, 2005, 86 (22) :1-3
[4]   Polarization fatigue in ferroelectric thin films and related materials [J].
Lou, X. J. .
JOURNAL OF APPLIED PHYSICS, 2009, 105 (02)
[5]   Ferroelectric, electrical and magnetic properties of Cr, Mn, Co, Ni, Cu added polycrystalline BiFeO3 films [J].
Naganuma, Hiroshi ;
Miura, Jun ;
Okamura, Soichiro .
APPLIED PHYSICS LETTERS, 2008, 93 (05)
[6]   Multiferroic magnetoelectric composites: Historical perspective, status, and future directions [J].
Nan, Ce-Wen ;
Bichurin, M. I. ;
Dong, Shuxiang ;
Viehland, D. ;
Srinivasan, G. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (03)
[7]   Microstructure and piezoelectric properties of the CuO-added (Na0.5K0.5)(Nb0.97Sb0.03)O3 lead-free piezoelectric ceramics [J].
Park, Hwi-Yeol ;
Seo, In-Tae ;
Choi, Min-Kyu ;
Nahm, Sahn ;
Lee, Hyeung-Gyu ;
Kang, Hyung-Won ;
Choi, Byung-Hyun .
JOURNAL OF APPLIED PHYSICS, 2008, 104 (03)
[8]   Greatly reduced leakage current and conduction mechanism in aliovalent-ion-doped BiFeO3 -: art. no. 062903 [J].
Qi, XD ;
Dho, J ;
Tomov, R ;
Blamire, MG ;
MacManus-Driscoll, JL .
APPLIED PHYSICS LETTERS, 2005, 86 (06) :1-3
[9]   Multiferroics: progress and prospects in thin films [J].
Ramesh, R. ;
Spaldin, Nicola A. .
NATURE MATERIALS, 2007, 6 (01) :21-29
[10]   Oxygen-vacancy ordering as a fatigue mechanism in perovskite ferroelectrics [J].
Scott, JF ;
Dawber, M .
APPLIED PHYSICS LETTERS, 2000, 76 (25) :3801-3803