Two-Dimensional Symmetrical Mixtures in an External Field of Square Symmetry

被引:5
作者
Patrykiejew, A. [1 ]
Sokolowski, S. [1 ]
机构
[1] MCS Univ, Fac Chem, Dept Modelling Physicochem Proc, PL-20031 Lublin, Poland
关键词
LENNARD-JONES SYSTEM; PHASE-TRANSITIONS; 2; DIMENSIONS; BEHAVIOR; SIMULATION; GAS; SEPARATION; MONOLAYER; DIAGRAM; MODEL;
D O I
10.1021/jp908710e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using the Monte Carlo simulation method in the grand canonical ensemble, we Study two-dimensional symmetrical binary mixtures subjected to all external potential of square symmetry and finite corrugation. The results reveal a rich variety of mixed liquid-like and solid-like structures. It is demonstrated that even very weakly corrugated external potential leads to the development of axially ordered striped solid-like phases. The results of finite temperature simulation Confirm quite well the predictions stemming from the ground state considerations and show the formation of commensurate, high-order commensurate, and incommensurate mixed phases. It is also shown that the corrugation potential affects the demixing transition.
引用
收藏
页码:396 / 406
页数:11
相关论文
共 55 条
[1]  
ABRAHAM FF, 1981, PHYS REP, V80, P339, DOI 10.1016/0370-1573(81)90099-5
[2]  
Allen M. P., 2017, COMPUTER SIMULATION
[3]   Phase diagram of symmetric binary fluid mixtures: First-order or second-order demixing [J].
Antonevych, O ;
Forstmann, F ;
Diaz-Herrera, E .
PHYSICAL REVIEW E, 2002, 65 (06) :1-061504
[4]   Binary crystals in two-dimensional two-component Yukawa mixtures [J].
Assoud, Lahcen ;
Messina, Rene ;
Loewen, Hartmut .
JOURNAL OF CHEMICAL PHYSICS, 2008, 129 (16)
[5]   PHASE-DIAGRAM OF THE TWO-DIMENSIONAL LENNARD-JONES SYSTEM - EVIDENCE FOR 1ST-ORDER TRANSITIONS [J].
BARKER, JA ;
HENDERSON, D ;
ABRAHAM, FF .
PHYSICA A, 1981, 106 (1-2) :226-238
[6]  
Binder K., 2001, Phase Transformations in Materials
[7]  
BINDER K, 1995, COHESION STRUCTURE S
[8]  
Bruch L. W., 1997, Physical Adsorption: Forces and Phenomena
[9]   HELMHOLTZ FREE-ENERGY FOR 2-DIMENSIONAL LENNARD-JONES FLUIDS [J].
CUADROS, F ;
MULERO, A .
CHEMICAL PHYSICS, 1993, 177 (01) :53-60
[10]  
Dash J.G., 1980, PHASE TRANSITIONS SU