Comparative life cycle studies on poly(3-hydroxybutyrate)-based composites as potential replacement for conventional petrochemical plastics

被引:87
作者
Pietrini, Matteo
Roes, Lex
Patel, Martin K.
Chiellini, Emo
机构
[1] Univ Utrecht, Copernicus Inst, Dept Sci Technol & Soc, NL-3584 CS Utrecht, Netherlands
[2] Univ Pisa, Dept Chem & Ind Chem, UdR INSTM, Lab Bioact Polymer Mat Biomed & Environm Applicat, I-56126 Pisa, Italy
关键词
D O I
10.1021/bm0700892
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A cradle-to-grave environmental life cycle assessment (LCA) of a few poly(3-hydroxybutyrate) (PHB) based composites has been performed and was compared to commodity petrochemical polymers. The end products studied are a cathode ray tube (CRT) monitor housing (conventionally produced from high-impact polystyrene, HIPS) and the internal panels of an average car (conventionally produced from glass-fibers-filled polypropylene, PP-GF). The environmental impact is evaluated on the basis of nonrenewable energy use (NREU) and global warming potential over a 100 years time horizon (GWP100). Sugar cane bagasse (SCB) and nanoscaled organophilic montmorillonite (OMMT) are used as PHB fillers. The results obtained show that, despite the unsatisfying mechanical properties of PHB composites, depending on the type of filler and on the product, it is possible to reach lower environmental impacts than by use of conventional petrochemical polymers. These savings are mainly related to the PHB production process, while there are no improvements related to composites preparation. SCB-based composites seem to be environmentally superior to clay-based ones.
引用
收藏
页码:2210 / 2218
页数:9
相关论文
共 47 条
[11]   Factorial design in optimization of PHAs processing [J].
Chiellini, E ;
Fernandes, EG ;
Pietrini, M ;
Solaro, R .
MACROMOLECULAR SYMPOSIA, 2003, 197 :45-55
[12]   Preparation and characterization of poly(hydroxybutyrate-co-hydroxyvalerate)-organoclay nanocomposites [J].
Choi, WM ;
Kim, TW ;
Park, OO ;
Chang, YK ;
Lee, JW .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (02) :525-529
[13]   Life cycle assessment of biofibres replacing glass fibres as reinforcement in plastics [J].
Corbière-Nicollier, T ;
Gfeller-Laban, B ;
Lundquist, L ;
Leterrier, Y ;
Månson, JAE ;
Jolliet, O .
RESOURCES CONSERVATION AND RECYCLING, 2001, 33 (04) :267-287
[14]  
Diener J, 1999, ANGEW MAKROMOL CHEM, V272, P1
[15]   Thermo-mechanical and morphological characterization of plasticized poly [(R)-3-hydroxybutyric acid] [J].
Fernandes, EG ;
Pietrini, M ;
Chiellini, E .
MACROMOLECULAR SYMPOSIA, 2004, 218 :157-164
[16]   Bio-based polymeric composites comprising wood flour as filler [J].
Fernandes, EG ;
Pietrini, M ;
Chiellini, E .
BIOMACROMOLECULES, 2004, 5 (04) :1200-1205
[17]  
FERNANDES EG, IN PRESS
[18]  
FRISCHKNECHT R, 2003, 6 PAUL SCHER I VILL
[19]   Can biotechnology move us toward a sustainable society? [J].
Gerngross, TU .
NATURE BIOTECHNOLOGY, 1999, 17 (06) :541-544
[20]  
Gutowski T., 2006, P 13 CIRP INT C LIFE, V31, P623