A Lab-to-Fab Study toward Roll-to-Roll Fabrication of Reproducible Perovskite Solar Cells under Ambient Room Conditions

被引：55

作者：

Angmo, Dechan ^{[1
]}

DeLuca, Giovanni ^{[2
]}

Scully, Andrew D. ^{[1
]}

Chesman, Anthony S. R. ^{[1
]}

Seeber, Aaron ^{[1
]}

Zuo, Chuantian ^{[1
]}

Vak, Doojin ^{[1
]}

Bach, Udo ^{[2
]}

Gao, Mei ^{[1
]}

机构：

[1] CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia

[2] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia

来源：

CELL REPORTS PHYSICAL SCIENCE | 2021年 / 2卷 / 01期

基金：

美国国家科学基金会;

关键词：

LOW-COST; EFFICIENT; FILMS; DEPOSITION;

D O I：

10.1016/j.xcrp.2020.100293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The low power-conversion efficiency (PCE) and reproducibility reported to date for roll-to-roll (R2R)-fabricated perovskite solar cells (PSCs) results from difficulty in controlling perovskite film quality. Here, we present a systematic comparison of the hot deposition method, which induces crystal-growth-driven (CGD) film formation, and the anti-solvent method, which induces nucleation-driven (ND) film formation, for one-step perovskite film formation. Perovskite films produced by the two methods show markedly different micro-structural and optoelectronic properties; however, PCEs of CGD-type PSCs are only marginally lower than those of ND-type PSCs. Importantly, the average performance of PSCs incorporating a CGD-type perovskite layer is independent of humidity during fabrication and displays improved stability and reproducibility, prompting further investigation of upscaling potential. R2R-produced PSCs on plastic substrate with four slot-die-coated functional layers show superior reproducibility and micro-structural, optoelectronic, and photovoltaic properties comparable with those of glassbased PSCs, indicating excellent promise for translation to a manufacturing process.

引用

页数：18

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