A Lab-to-Fab Study toward Roll-to-Roll Fabrication of Reproducible Perovskite Solar Cells under Ambient Room Conditions

被引:49
作者
Angmo, Dechan [1 ]
DeLuca, Giovanni [2 ]
Scully, Andrew D. [1 ]
Chesman, Anthony S. R. [1 ]
Seeber, Aaron [1 ]
Zuo, Chuantian [1 ]
Vak, Doojin [1 ]
Bach, Udo [2 ]
Gao, Mei [1 ]
机构
[1] CSIRO Mfg, Flexible Elect Lab, Clayton, Vic 3168, Australia
[2] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
来源
CELL REPORTS PHYSICAL SCIENCE | 2021年 / 2卷 / 01期
基金
美国国家科学基金会;
关键词
LOW-COST; EFFICIENT; FILMS; DEPOSITION;
D O I
10.1016/j.xcrp.2020.100293
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The low power-conversion efficiency (PCE) and reproducibility reported to date for roll-to-roll (R2R)-fabricated perovskite solar cells (PSCs) results from difficulty in controlling perovskite film quality. Here, we present a systematic comparison of the hot deposition method, which induces crystal-growth-driven (CGD) film formation, and the anti-solvent method, which induces nucleation-driven (ND) film formation, for one-step perovskite film formation. Perovskite films produced by the two methods show markedly different micro-structural and optoelectronic properties; however, PCEs of CGD-type PSCs are only marginally lower than those of ND-type PSCs. Importantly, the average performance of PSCs incorporating a CGD-type perovskite layer is independent of humidity during fabrication and displays improved stability and reproducibility, prompting further investigation of upscaling potential. R2R-produced PSCs on plastic substrate with four slot-die-coated functional layers show superior reproducibility and micro-structural, optoelectronic, and photovoltaic properties comparable with those of glassbased PSCs, indicating excellent promise for translation to a manufacturing process.
引用
收藏
页数:18
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