Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold

被引：26

作者：

Brown, Jessie L. ^{[1
]}

Gaunt, Andrew J. ^{[1
]}

King, David M. ^{[2
]}

Liddle, Stephen T. ^{[2
]}

Reilly, Sean D. ^{[1
]}

Scott, Brian L. ^{[3
]}

Wooles, Ashley J. ^{[2
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, POB 1663, Los Alamos, NM 87545 USA

[2] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England

[3] Los Alamos Natl Lab, Mat Phys & Applicat Div, POB 1663, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 31期

基金：

英国工程与自然科学研究理事会;

关键词：

LIGAND MULTIPLE BONDS; SE; URANIUM(V); CHEMISTRY; ACTINIDE; ANALOGS; ION; TE;

D O I：

10.1039/c6cc01656a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses and characterisation of isostructural neptunium(IV) and plutonium(IV) complexes [An(IV)(TRENTIPS)(Cl)] [An = Np, Pu; TRENTIPS = {N(CH2CH2NSiPr3i)(3)}(3-)] are reported, along with the demonstration that they are likely reduced to the corresponding neptunium(III) and plutonium(III) products [An(III)(TRENTIPS)]; this chemistry provides new platforms fromwhich to target a plethora of unprecedented molecular functionalities in transuranic chemistry and the neptunium(IV) molecule is the first structurally characterised neptunium(IV)-amide complex.

引用

页码：5428 / 5431

页数：4

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