Facile synthesis and characterization of magnetic nanocomposite ZnO/CoFe2O4 hetero-structure for rapid photocatalytic degradation of imidacloprid

被引:50
作者
Naghizadeh, Matin [1 ,2 ]
Taher, Mohammad Ali [1 ]
Tamaddon, Ali-Mohammad [3 ,4 ]
机构
[1] Shahid Bahonar Univ Kerman, Dept Chem, Kerman, Iran
[2] Shahid Bahonar Univ Kerman, Young Researchers Soc, Kerman, Iran
[3] Shiraz Univ Med Sci, Ctr Nanotechnol Drug Delivery, Shiraz, Iran
[4] Shiraz Univ Med Sci, Sch Pharm, Dept Pharmaceut, Shiraz, Iran
关键词
Analytical chemistry; Environmental science; Materials chemistry; ZnO/CoFe2O4 magnetic nanocomposite; Imidacloprid; Photocatalytic degradation; Water pollution; HETEROGENEOUS FENTON CATALYST; NANOPARTICLES; SOIL; PESTICIDES; PHOTODEGRADATION; GRAPHITE; WATER; FE2+;
D O I
10.1016/j.heliyon.2019.e02870
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
This work has attempted to investigate the potential of ZnO/CoFe2O4 magnetic nanocomposite to mineralize imidacloprid completely to have sustainable pollutant free and safe water supply. The co-precipitation method was performed to prepare the composites; was performed to characterize composites, scanning electron microscope (SEM), transmission electron microscopy (TEM), energy dispersive x-ray crystallography (EDX), x-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and vibrating sample magnetometer (VSM). It was attempted to explore and enhance parameters influencing the process and the percentage of imidacloprid degradation, including photocatalyst amount, pesticide concentration, pH, radiation time, and temperature. UV-Vis spectrophotometer was used for the degradation percent of organochlorine pesticides. Parameters affecting the process, including photocatalyst amount, pesticide concentration, pH, radiation time, and temperature effect on the percentage of imidacloprid degradation were Investigated and optimized. 0.05 g of photocatalyst, with a concentration of 5 ppm for 45 min under light exposure was obtained at pH 10 a room temperature.
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页数:12
相关论文
共 36 条
  • [1] Biodegradation of imidacloprid by an isolated soil microorganism
    Anhalt, Jennifer C.
    Moorman, Thomas B.
    Koskinen, William C.
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES, 2007, 42 (05) : 509 - 514
  • [2] Predicting the probability and volume of postwildfire debris flows in the intermountain western United States
    Cannon, Susan H.
    Gartner, Joseph E.
    Rupert, Michael G.
    Michael, John A.
    Rea, Alan H.
    Parrett, Charles
    [J]. GEOLOGICAL SOCIETY OF AMERICA BULLETIN, 2010, 122 (1-2) : 127 - 144
  • [3] Removal of azo dye CI Acid Red 14 from contaminated water using fenton, UV/H2O2, UV/H2O2/Fe(II), UV/H2O2/Fe(III) and UV/H2O2/Fe(III)/oxalate processes:: A comparative study
    Daneshvar, N
    Khataee, AR
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2006, 41 (03): : 315 - 328
  • [4] Magnetic CoFe2O4 nanoparticles supported on titanate nanotubes (CoFe2O4/TNTs) as a novel heterogeneous catalyst for peroxymonosulfate activation and degradation of organic pollutants
    Du, Yunchen
    Ma, Wenjie
    Liu, Pingxin
    Zou, Bohua
    Ma, Jun
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2016, 308 : 58 - 66
  • [5] Effiong J. B., 2015, Global Journal of Pure and Applied Sciences, V21, P105, DOI 10.4314/gjpas.v21i2.2
  • [6] Status of pesticides pollution in Tanzania - A review
    Elibariki, Raheli
    Maguta, Mihayo Musabila
    [J]. CHEMOSPHERE, 2017, 178 : 154 - 164
  • [7] Photocatalytic degradation of imidacloprid by composite catalysts H3PW12O40/La-TiO2
    Feng Changgen
    Xu Gang
    Liu Xia
    [J]. JOURNAL OF RARE EARTHS, 2013, 31 (01) : 44 - 48
  • [8] Novel Green Route of Synthesis of ZnO Nanoparticles by Using Natural Biodegradable Polymer and Its Application as a Catalyst for Oxidation of Aldehydes
    Handore, Kalpana
    Bhavsar, Sanjay
    Horne, Amit
    Chhattise, Prakash
    Mohite, Kakasaheb
    Ambekar, Jalinder
    Pande, Nishigandh
    Chabukswar, Vasant
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2014, 51 (12): : 941 - 947
  • [9] Room-temperature ultraviolet nanowire nanolasers
    Huang, MH
    Mao, S
    Feick, H
    Yan, HQ
    Wu, YY
    Kind, H
    Weber, E
    Russo, R
    Yang, PD
    [J]. SCIENCE, 2001, 292 (5523) : 1897 - 1899
  • [10] Photo-catalytic degradation of methyl violet dye using zinc oxide nano particles prepared by a novel precipitation method and its anti-bacterial activities
    Jeyasubramanian, K.
    Hikku, G. S.
    Sharma, R. Krishna
    [J]. JOURNAL OF WATER PROCESS ENGINEERING, 2015, 8 : 35 - 44