A highly effective (triphenyl phosphite)palladium catalyst for a cross-coupling reaction of allylic alcohols with organoboronic acids

被引：81
|
作者：
Kayaki, Y
Koda, T
Ikariya, T
机构：
[1] Tokyo Inst Technol, Grad Sch Sci & Technol, Meguro Ku, Tokyo 1528552, Japan
[2] Tokyo Inst Technol, Frontier Collaborat Res Ctr, Meguro Ku, Tokyo 1528552, Japan
[3] PRESTO, Japan Sci & Technol Agcy, Meguro Ku, Tokyo 1528552, Japan
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 2004卷 / 24期
关键词：
allylation; boranes; C-C coupling; green chemistry; palladium;
D O I：
10.1002/ejoc.200400621
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cross coupling reaction of aryl and vinyl boronic acids and allylic alcohols proceeded smoothly in toluene or dioxane in the presence of a (triphenyl phosphite) palladium catalyst to give the corresponding allylbenzene derivatives and 1,4-dienes. Neither cocatalysts for promoting C-O bond cleavage of allylic alcohols nor bases for activation of organoboron reagents are required for promoting the coupling process. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码：4989 / 4993
页数：5
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