Contrasting nanoseale surface morphologies of polyurethanes containing polyoxetane soft blocks with random and block segmer sequences

被引:26
作者
Fujiwara, T [1 ]
Wynne, KJ [1 ]
机构
[1] Virginia Commonwealth Univ, Dept Chem Engn, Richmond, VA 23284 USA
关键词
D O I
10.1021/ma048747n
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of shock block sequence distribution on surface morphology and wetting behavior was analyzed. It was observed that polyurethanes such as PU-1 were highly effective in modification of the surface of conventional polyurethanes. It was also observed that the polyurethanes were prepared using polyoxetane telechelics or a reference PTMO soft segment. It was found that polyurethanes had different nanoscale morphologies and water contact angle was dependent on soft segment sequence.
引用
收藏
页码:8491 / 8494
页数:4
相关论文
共 32 条
[1]   Multihydroxyl branched polyethers. 2. Mechanistic aspects of cationic polymerization of 3-ethyl-3-(hydroxymethyl)oxetane [J].
Bednarek, M ;
Kubisa, P ;
Penczek, S .
MACROMOLECULES, 2001, 34 (15) :5112-5119
[2]  
BERTOLUCCI M, 2002, POLYM PREPR, V43, P647
[3]   CO-POLYMERIZATION OF OXETANE WITH 3,3-DIMETHYLOXETANE .1. REACTIVITY PARAMETERS AND MICROSTRUCTURE OF COPOLYMERS [J].
BUCQUOYE, M ;
GOETHALS, EJ .
EUROPEAN POLYMER JOURNAL, 1978, 14 (05) :323-328
[4]   Surface modification of polyethylene films via bromination: Reactions of brominated polyethylene with aromatic thiolate compounds [J].
Chanunpanich, N ;
Ulman, A ;
Malagon, A ;
Strzhemechny, YM ;
Schwarz, SA ;
Janke, A ;
Kratzmueller, T ;
Braun, HG .
LANGMUIR, 2000, 16 (07) :3557-3560
[5]   Interaction of fibrinogen with surfaces of end-group-modified polyurethanes: A surface-specific sum-frequency-generation vibrational spectroscopy study [J].
Chen, Z ;
Ward, R ;
Tian, Y ;
Malizia, F ;
Gracias, DH ;
Shen, YR ;
Somorjai, GA .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 2002, 62 (02) :254-264
[6]   Synthesis and characterization of novel Amphiphilic telechelic polyoxetanes [J].
Fujiwara, T ;
Makal, U ;
Wynne, KJ .
MACROMOLECULES, 2003, 36 (25) :9383-9389
[7]   Microdomain morphology of poly(urethane urea) multiblock copolymers [J].
Garrett, JT ;
Siedlecki, CA ;
Runt, J .
MACROMOLECULES, 2001, 34 (20) :7066-7070
[8]   Plasma treatment of polymers [J].
Grace, JM ;
Gerenser, LJ .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2003, 24 (3-4) :305-341
[9]   Synthesis and characterization of non-leaching biocidal polyurethanes [J].
Grapski, JA ;
Cooper, SL .
BIOMATERIALS, 2001, 22 (16) :2239-2246
[10]   CHARACTERIZATION OF ALKYL GRAFTED POLYURETHANE BLOCK COPOLYMERS BY VARIABLE TAKEOFF ANGLE X-RAY PHOTOELECTRON-SPECTROSCOPY [J].
GRASEL, TG ;
CASTNER, DG ;
RATNER, BD ;
COOPER, SL .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1990, 24 (05) :605-620