Contrasting nanoseale surface morphologies of polyurethanes containing polyoxetane soft blocks with random and block segmer sequences

被引:26
作者
Fujiwara, T [1 ]
Wynne, KJ [1 ]
机构
[1] Virginia Commonwealth Univ, Dept Chem Engn, Richmond, VA 23284 USA
关键词
D O I
10.1021/ma048747n
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of shock block sequence distribution on surface morphology and wetting behavior was analyzed. It was observed that polyurethanes such as PU-1 were highly effective in modification of the surface of conventional polyurethanes. It was also observed that the polyurethanes were prepared using polyoxetane telechelics or a reference PTMO soft segment. It was found that polyurethanes had different nanoscale morphologies and water contact angle was dependent on soft segment sequence.
引用
收藏
页码:8491 / 8494
页数:4
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