The enantioselective synthesis of α-amino acids by phase-transfer catalysis with achiral Schiff base esters

被引：681
作者：
O'Donnell, MJ [1 ]
机构：
[1] Indiana Univ Purdue Univ, Univ Indianapolis, Dept Chem, Indianapolis, IN 46202 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2004年 / 37卷 / 08期
关键词：
D O I：
10.1021/ar0300625
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The development and application of chiral phase-transfer catalysis (PTC) for the enantioselective synthesis of optically active alpha-amino acid derivatives using achiral Schiff base esters developed in the author's laboratory and by others is reviewed. Phase-transfer catalysts derived from the Cinchona alkaloids have been exploited as inexpensive and attractive organocatalysts in the chiral PTC process. The recent evolution and use of these and other catalytic systems is described.
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页码：506 / 517
页数：12
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