Lithium cations in a self-assembled electrostatic nanocapsule

被引：6

作者：

Mayans, Julia ^{[1
,2
]}

Font-Bardia, Merce ^{[3
,4
]}

Escuer, Albert ^{[1
,2
]}

机构：

[1] Univ Barcelona, SeccioInorgan, Dept Quim Inorgan & Organ, Marti & Franques 1-11, E-08028 Barcelona, Spain

[2] Univ Barcelona, IN2UB, Marti & Franques 1-11, E-08028 Barcelona, Spain

[3] Univ Barcelona, Ctr Cient & Tecnol, Dept Mineral Cristallog DipositsMinerals, Sole & Sabaris 1-3, E-08028 Barcelona, Spain

[4] Univ Barcelona, Ctr Cient & Tecnol, Unitat Offraccio R X, Sole & Sabaris 1-3, E-08028 Barcelona, Spain

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 43期

关键词：

COMPLEXES; CLUSTERS; LIGAND;

D O I：

10.1039/c9dt03600h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cascade self-assembly of small components, without the employment of preformed hosts, yielded a {Ni12Li2} nanometric capsule with multiple endo- and exo-guests (water molecules, Li+, and Et3NH+ cations) linked to selective hydrophilic and hydrophobic binding sites of Ni-II hexanuclear metallamacrocycles. The synthesis was achieved by using (Bu4N)N-3 as a starting reagent instead of the conventional sodium azide to selectively introduce the Li+ cations.

引用

页码：16158 / 16161

页数：4

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