Lithium cations in a self-assembled electrostatic nanocapsule

被引:6
作者
Mayans, Julia [1 ,2 ]
Font-Bardia, Merce [3 ,4 ]
Escuer, Albert [1 ,2 ]
机构
[1] Univ Barcelona, SeccioInorgan, Dept Quim Inorgan & Organ, Marti & Franques 1-11, E-08028 Barcelona, Spain
[2] Univ Barcelona, IN2UB, Marti & Franques 1-11, E-08028 Barcelona, Spain
[3] Univ Barcelona, Ctr Cient & Tecnol, Dept Mineral Cristallog DipositsMinerals, Sole & Sabaris 1-3, E-08028 Barcelona, Spain
[4] Univ Barcelona, Ctr Cient & Tecnol, Unitat Offraccio R X, Sole & Sabaris 1-3, E-08028 Barcelona, Spain
关键词
COMPLEXES; CLUSTERS; LIGAND;
D O I
10.1039/c9dt03600h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Cascade self-assembly of small components, without the employment of preformed hosts, yielded a {Ni12Li2} nanometric capsule with multiple endo- and exo-guests (water molecules, Li+, and Et3NH+ cations) linked to selective hydrophilic and hydrophobic binding sites of Ni-II hexanuclear metallamacrocycles. The synthesis was achieved by using (Bu4N)N-3 as a starting reagent instead of the conventional sodium azide to selectively introduce the Li+ cations.
引用
收藏
页码:16158 / 16161
页数:4
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