A convenient method for preparing rigid-core ionic liquid crystals

被引：25

作者：

Fouchet, Julien ^{[1
]}

Douce, Laurent ^{[1
]}

Heinrich, Benoit ^{[1
]}

Welter, Richard ^{[2
]}

Louati, Alain ^{[3
]}

机构：

[1] Univ Strasbourg, CNRS, DMO, UMR 7504,Inst Phys & Chim Mat Strasbourg, F-67034 Strasbourg 2, France

[2] Univ Strasbourg, CNRS, UMR 7177, LC003,Lab DECOMET, F-67000 Strasbourg, France

[3] Ecole Natl Super Chim, Lab Electrochim Analyt, F-68093 Mulhouse, France

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 5卷

关键词：

imidazolium; ionic liquid crystals; Ullman reaction; IMIDAZOLIUM SALTS; MESOMORPHIC PROPERTIES;

D O I：

10.3762/bjoc.5.51

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient, solvent free method for the N-arylation of imidazole by 1-(dodecyloxy)-4-iodobenzene using Cu(II)-NaY as catalyst and K2CO3 as base is reported. By this synthetic approach, mesomorphic 3-[4-(dodecyloxy)phenyl]-1-methyl-1H-imidazol-3-ium iodide was synthesized in a two-step procedure, and its mesomorphism has been fully investigated by polarised optical microscopy, differential scanning calorimetry and X-ray diffraction. In addition its lamellar crystal structure, electrochemical behaviour and UV (absorption and emission) properties are reported.

引用

页数：10

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