Light-Induced Formation of Thymine-Containing Mercury(II)-Mediated Base Pairs

被引：7

作者：

Naskar, Shuvankar ^{[1
]}

Mueller, Jens ^{[1
]}

机构：

[1] Westfalische Wilhelms Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 30, D-48149 Munster, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2019年 / 25卷 / 71期

关键词：

bioinorganic chemistry; caged nucleosides; metal-mediated base pairs; nucleic acids; thymidine; HG-II-T; DNA DUPLEXES; IONS;

D O I：

10.1002/chem.201903789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By applying caged thymidine residues, DNA duplexes were created in which Hg-II-mediated base pair formation can be triggered by irradiation with light. When a bidentate ligand was used as the complementary nucleobase, an unprecedented stepwise formation of different metal-mediated base pairs was achieved.

引用

页码：16214 / 16218

页数：5

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