Carbon-carbon bond formation via thermal intermolecular hydrogen atom transfer:: two serendipitous heterocyclic examples

被引：0
|
作者：
Hamlyn, RJ [1 ]
Jones, RH [1 ]
Ramsden, CA [1 ]
机构：
[1] Univ Keele, Sch Chem & Phys, Keele ST5 5BG, Staffs, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 12期
关键词：
D O I：
10.1039/a909891g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Formation of an anomalous 3-nitrothiophene product, encountered during the preparation of potential bioreductive anti-cancer agents, is rationalised in terms of a hydrogen atom transfer mechanism which also accounts for the unexpected formation of previously described 5,5'-biimidazoles.
引用
收藏
页码：1811 / 1813
页数：3
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