Crystal structure of K2[UO2(C2O4)(SO4)]•3H2O

被引：0
|
作者：
Artem'eva, MY [1 ]
Vologzhanina, AV
Dolgushin, FM
Antipin, MY
Serezhkina, LB
Serezhkin, VN
机构：
[1] Samara State Univ, Samara 443086, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 117813, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 12期
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The single crystals of K-2[UO2(C2O4)(SO4)] (.) 3H(2)O were studied by X-ray diffraction. The compound crystallizes in the triclinic system; its unit cell parameters are a = 5.743(1) Angstrom, b = 9.544(2) Angstrom, c = 11.845(2) Angstrom, alpha = 89.49(3)degrees, beta = 84.95(3)degrees, gamma = 83.01(3)degrees, space group P (1) over bar, Z = 2, R = 0.024. The structure contains infinite zigzaglike chains [UO2(C2O4)(SO4)](2-) stretched along the [100] direction and corresponding to the crystal-chemical group AK(02)M(1) (A = UO22+) of uranyl complexes. The chains are linked to one another through electrostatic interactions with potassium ions and through hydrogen bonds involving outer-sphere water molecules.
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页码：1917 / 1922
页数：6
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