Synthesis, characterization, and catalytic behavior of mono- and bimetallic ruthenium(II) and iridium(III) complexes supported by pyridine-functionalized N-heterocyclic carbene ligands

被引：8
作者：
Smith, Isaac G. [1 ]
Zgrabik, Joshua C. [1 ]
Gutauskas, Alexa C. [1 ,4 ]
Gray, Danielle L. [2 ,3 ]
Domski, Gregory J. [1 ]
机构：
[1] Augustana Coll, Rock Isl, IL 61201 USA
[2] Univ Illinois, George L Clark Xray Facil, Chicago, IL 60680 USA
[3] Univ Illinois, Mat Lab 3M, Chicago, IL 60680 USA
[4] Univ Illinois, Coll Vet Med, Chicago, IL 60680 USA
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 81卷
关键词：
N-heterocyclic carbene; Ruthenium(II); Iridium(III); Transfer hydrogenation; Bimetallic; DEPENDENT COORDINATION MODES; PALLADIUM COMPLEXES; TRANSFER HYDROGENATION; EFFICIENT CATALYSTS; COUPLING REACTIONS; METAL; TRANSITION; COMMUNICATION; IMIDAZOLIUM; REDUCTION;
D O I：
10.1016/j.inoche.2017.04.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We have prepared and characterized five unreported ruthenium(II) and iridium(III) complexes supported by pyridine-functionalized N-heterocyclic carbene ligands including a bimetallic iridium(III) complex. When activated, all complexes are active catalysts for the transfer hydrogenation of acetophenone. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：27 / 32
页数：6
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