A three-dimensional open-framework germanate containing four-, five- and six-coordinated germanium

被引：26
|
作者：
Sun, K [1 ]
Dadachov, MS [1 ]
Conradsson, T [1 ]
Zou, XD [1 ]
机构：
[1] Stockholm Univ, S-10691 Stockholm, Sweden
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷
关键词：
D O I：
10.1107/S0108270100009057
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new three-dimensional open-framework germanate, namely ethylenediamine bis(ethylenediammonium) tetrahydroxooctadecaoxononagermanate, (C2H8N2)(C2H10N2)(2)[Ge9O18(OH)(4)], has been synthesized hydrothermally and its structure determined by single-crystal X-ray diffraction. The framework is built of [Ge9O22(OH)(4)] units formed by four-, five- and six-oxygen-coordinated germanium and templated by ethylenediamine. Three types of intersecting channels are formed in the framework, one by eight-membered rings running along the b axis and the other two by ten-membered rings running parallel to the a and c axes, respectively.
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收藏
页码：1092 / 1094
页数：3
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