Novel initiating system based on AlCl3 etherate for quasiliving cationic polymerization of styrene

被引：29
作者：
Kostjuk, SV
Dubovik, AY
Vasilenkol, IV
Mardykin, VP
Gaponik, LV
Kaputsky, FN
Antipin, LM
机构：
[1] Belarusian State Univ, Phys Chem Problems Res Inst, Minsk 220050, BELARUS
[2] Russian Acad Sci, Inst Phys Chem, Moscow 119991, Russia
来源：
POLYMER BULLETIN | 2004年 / 52卷 / 3-4期
关键词：
D O I：
10.1007/s00289-004-0280-2
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Quasiliving cationic polymerization of styrene was obtained in the system 2-phenyl-2-propano-/AlCl3.OBu2/Bu2O in a mixture of 1,2-dichloroethane and n-hexane (55:45 viv) at -15degreesC. The molecular weights of the polymers (M-n) increased in direct proportion to the monomer conversion. However, the experimental M(n)s are essentially higher than theoretical ones, indicating that slow initiation relative to propagation takes place. The molecular weight distributions were broad (M-w/M(n)similar to2.5), probably due to the slow initiation and slow exchange between reversibly terminated and propagating species.
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页码：227 / 234
页数：8
相关论文
共 31 条
[21]  
KOSTJUK SV, 2000, VESTSI NATL AKAD NAU, P47
[22]  
KOSTJUK SV, UNPUB
[23]   LIVING CARBOCATIONIC SEQUENTIAL BLOCK COPOLYMERIZATION OF ISOBUTYLENE WITH ALPHA-METHYLSTYRENE [J].
LI, DW ;
FAUST, R .
MACROMOLECULES, 1995, 28 (05) :1383-1389
[24]   Alkyl chloride-boron trichloride initiated polymerizations of isobutylene: Detailed analysis of the initial propagation steps [J].
Mayr, H ;
Roth, M .
MACROMOLECULAR SYMPOSIA, 1998, 132 :103-116
[25]   Living carbocationic polymerization of resonance-stabilized monomers [J].
Puskas, JE ;
Kaszas, G .
PROGRESS IN POLYMER SCIENCE, 2000, 25 (03) :403-452
[26]   Living oligomerization of isobutylene using di- and triisobutylene hydrochlorides as initiators [J].
Roth, M ;
Patz, M ;
Freter, H ;
Mayr, H .
MACROMOLECULES, 1997, 30 (04) :722-725
[27]   Direct synthesis of amphiphilic random and block copolymers of p-hydroxystyrene and p-methoxystyrene via living cationic polymerization with BF3OEt2/ROH systems [J].
Satoh, K ;
Kamigaito, M ;
Sawamoto, M .
MACROMOLECULES, 2000, 33 (16) :5830-5835
[28]   Novel BF3OEt2/R-OH initiating system for controlled cationic polymerization of styrene in the presence of water [J].
Satoh, K ;
Nakashima, J ;
Kamigaito, I ;
Sawamoto, M .
MACROMOLECULES, 2001, 34 (03) :396-401
[29]   MODERN CATIONIC VINYL POLYMERIZATION [J].
SAWAMOTO, M .
PROGRESS IN POLYMER SCIENCE, 1991, 16 (01) :111-172
[30]   ASPECTS OF THE SYNTHESIS OF POLY(STYRENE-B-ISOBUTYLENE-B-STYRENE) BLOCK-COPOLYMERS USING LIVING CARBOCATIONIC POLYMERIZATION [J].
STOREY, RF ;
CHISHOLM, BJ .
MACROMOLECULES, 1993, 26 (25) :6727-6733
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