Gamma-ray irradiation-induced variations in structural and electrical properties of PVP neutral polymer in water

被引：8
|
作者：
Belaidi, Amal [1 ,2 ]
Guettari, Moez [1 ]
Tajouri, Tahar [1 ]
机构：
[1] Univ Tunis, NMR Polymers & Composites Lab, Preparatory Inst Engn Studies Tunis, Tunis, Tunisia
[2] Univ Carthage, Fac Sci Bizerte, Carthage 7021, Tunisia
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2019年 / 322卷 / 02期
关键词：
Polyvinylpyrrolidone; Gamma irradiation; Electrical conductivity; PHYSICOCHEMICAL PROPERTIES; CONDUCTIVITY; CELLULOSE; POLYVINYLPYRROLIDONE; ELECTROLYTE; TRANSITION; CHITOSAN; UHMWPE; SUGAR;
D O I：
10.1007/s10967-019-06803-3
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The purpose of this study was to improve polyvinylpyrrolidone (PVP) electrical conductivity by means of gamma irradiation for a dosimetric application. PVP was irradiated with various doses of gamma radiation and dissolved in water to investigate its structural, optical, and electrical characteristics. Electron paramagnetic resonance measurements (EPR) depicted the presence of free radical (H-center dot). FTIR and UV-visible spectra revealed a structural deformation in the post-irradiated polymer (PVP*) through chain scission. In addition, the gap and Urbach energy were investigated and discussed. The obtained results of electrical conductivity show an exponential behavior indicating a character of a pseudo-polyelctrolyte. The pH measurements revealed an acidic character of PVP*.
引用
收藏
页码：869 / 877
页数：9
相关论文
共 50 条
  • [41] Characterization of amorphous silica nanofiller effect on the structural, morphological, optical, thermal, dielectric and electrical properties of PVA-PVP blend based polymer nanocomposites for their flexible nanodielectric applications
    Choudhary, Shobhna
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2018, 29 (12) : 10517 - 10534
  • [42] Structural, Morphological, Thermal, Dielectric, and Electrical Properties of Alumina Nanoparticles Filled PVA-PVP Blend Matrix-Based Polymer Nanocomposites
    Choudhary, Shobhna
    POLYMER COMPOSITES, 2018, 39 : E1788 - E1799
  • [43] Electron beam irradiation-induced transformations in the electrical properties of 4'-octyl-4-cyanobiphenyl (8CB)
    Verma, Rohit
    Dhar, R.
    Agrawal, V. K.
    Rath, M. C.
    Sarkar, S. K.
    Wadhawan, V. K.
    Dabrowski, R.
    LIQUID CRYSTALS, 2009, 36 (09) : 1003 - 1014
  • [44] Ion Irradiation-Induced Modification of Electrical Properties of YBa2Cu3O7-x NanoSQUIDs
    Lin, JianXin
    Wang, Qimin
    Zhang, Deheng
    Shi, Zejun
    Zhao, Lianjun
    Qing, Shenhao
    JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 2022, 35 (10) : 2671 - 2677
  • [45] GAMMA-RAY IRRADIATION EFFECT ON MECHANICAL AND DIELECTRIC PROPERTIES OF VOLCANIC BASALT MINERAL REINFORCED LOW DENSITY POLYETHYLENE FILMS
    Kilic, Mehmet
    Karabul, Yasar
    Alkan, Umit
    Yagci, Ozlem
    Okutan, Murat
    Okutan, Mustafa
    Icelli, Orhan
    PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING, 2017, 53 (01): : 578 - 590
  • [46] Electrical conductivity and gamma-ray response to clay, water and chloride content in fissured sediments, Trans-Pecos Texas
    Paine, JG
    Goldsmith, RS
    Scanlon, BR
    ENVIRONMENTAL & ENGINEERING GEOSCIENCE, 1998, 4 (02) : 225 - 239
  • [47] Effect of ionic liquid on structural, thermal and electrical transport properties of PVA-PVP based polymer blend electrolyte membrane
    Singh, Pankaj
    Saroj, A. L.
    PHYSICA SCRIPTA, 2021, 96 (11)
  • [48] RETRACTED: Structural and Electrical Properties of Graphene Oxide-Doped PVA/PVP Blend Nanocomposite Polymer Films (Retracted Article)
    Basha, S. K. Shahenoor
    Kumar, K. Vijay
    Sundari, G. Sunita
    Rao, M. C.
    ADVANCES IN MATERIALS SCIENCE AND ENGINEERING, 2018, 2018
  • [49] Gamma-irradiation-induced micro-structural variations in flame-retardant polyurethane foam using synchrotron X-ray micro-tomography
    Agrawal, A. K.
    Singh, B.
    Kashyap, Y. S.
    Shukla, M.
    Manjunath, B. S.
    Gadkari, S. C.
    JOURNAL OF SYNCHROTRON RADIATION, 2019, 26 : 1797 - 1807
  • [50] Gamma irradiation-induced effects on the properties of TiO2 on fluorine-doped tin oxide prepared by atomic layer deposition
    Syed Mansoor Ali
    M. S. Algarawi
    Turki S. ALKhuraiji
    S. S. Alghamdi
    Muhammad Hammad Aziz
    M. Isa
    Nuclear Science and Techniques, 2018, 29
12345