trans-Diapuabis(6-hydroxypicolinato-κ2N,O2)copper(II)

被引：20
作者：
Sengül, A
Büyükgüngör, O
机构：
[1] Ondokuz Mayis Univ, Dept Phys, TR-55139 Samsun, Turkey
[2] Zonguldak Karaelmas Univ, Dept Chem, TR-67100 Zonguldak, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270104031178
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, [Cu(C6H4NO3)(2)(H2O)(2)], the Cu-II ion lies on an inversion centre and has an elongated octahedral environment, equatorially trans-coordinated by two N,O-bidentate picolinate ligands and axially coordinated by two water O atoms. The complex molecules form layers, which are linked by O-H...O hydrogen bonds between the aqua ligands and neighbouring carboxylate groups. An intramolecular hydrogen bond between the coordinated carboxylate O atom and the hydroxy H atom is also observed.
引用
收藏
页码：M119 / M121
页数：3
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