Enantioselective isomerization of allylamine to enamine: practical asymmetric synthesis of (-)-menthol by Rh-BINAP catalysts

被引：46
作者：
Akutagawa, S [1 ]
机构：
[1] Takasago Int Corp, Minato Ku, Tokyo 108, Japan
来源：
TOPICS IN CATALYSIS | 1997年 / 4卷 / 3-4期
关键词：
allylamine; asymmetric synthesis; BINAP; chiral ligand; homogeneous catalysis; isomerization; isoprenoid amine; (-)-menthol; rhodium;
D O I：
10.1023/A:1019112911246
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Enantioselective isomerizations of allylamines to enamines are summarized from idea to industry. The Rh-BINAP catalyst reveals high selectivities, 99% yield and 98% enantiomer excess and high activity, TON > 400,000. Its industrial use for the production of a 1,500 t/y scale of (-)-menthol is introduced emphasizing technical development.
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页码：271 / 274
页数：4
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