Catalyst free visible light induced cycloaddition as an avenue for polymer ligation

被引：51
作者：
Lederhose, Paul [1 ,2 ,3 ]
Wuest, Kilian N. R. [2 ,3 ,4 ]
Barner-Kowollik, Christopher [1 ,2 ,3 ]
Blinco, James P. [1 ]
机构：
[1] Queensland Univ Technol, Fac Sci & Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia
[2] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, Preparat Macromol Chem, Engesserstr 18, D-76128 Karlsruhe, Germany
[3] Karlsruhe Inst Technol, Inst Biol Grenzflachen, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
[4] Univ New S Wales, Sch Chem, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 35期
关键词：
PHOTOCLICK CHEMISTRY; DESIGN;
D O I：
10.1039/c6cc00942e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The current study introduces a tetrazole species able to perform a rapid, visible light induced nitrile imine-mediated tetrazole-ene cycloaddition (NITEC). Full conversion of the tetrazole species under mild, catalyst free conditions is reported. Importantly, the visible light ligation technology is applied as a method for the modification and ligation of polymers featuring the rapid, clean and exclusive formation of the desired cycloadduct.
引用
收藏
页码：5928 / 5931
页数：4
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