Study of the process of poly(phenylquinoxaline)s formation in supercritical carbon dioxide

被引:9
作者
Belomoina, Nataliya M. [1 ]
Bulycheva, Elena G. [1 ]
Nikitin, Lev N. [1 ]
Vasil'ev, Viktor G. [1 ]
Elmanovich, Igor V. [1 ,3 ]
Bruma, Maria [2 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov St 28, Moscow 119991, Russia
[2] Petru Poni Inst Macromol Chem, Aleea Grigore Ghica Voda 41A, Iasi 700487, Romania
[3] Moscow MV Lomonosov State Univ, Fac Phys, Leninskie Gory 1-2, Moscow 119991, Russia
关键词
Poly(phenylquinoxaline)s; Supercritical carbon dioxide; Catalyst of cyclopolycondensation; Mechanical properties; POLYIMIDES; POLYMERS;
D O I
10.1016/j.supflu.2016.03.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A study of the formation of poly(phenylquinoxaline)s in supercritical carbon dioxide was performed. It was found that the reaction conditions of cyclopolycondensation had a significant impact on the formation of polymers. When using certain catalysts, soluble polymers were obtained which were cast into thin films and some of their properties were then studied. (C) 2016 Elsevier B.V. All rights reserved,
引用
收藏
页码:66 / 71
页数:6
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