A Novel Poly(vinylidene fluoride)-Based 4-Miktoarm Star Terpolymer: Synthesis and Self-Assembly

被引：20
|
作者：
Patil, Yogesh
Bilalis, Panayiotis
Polymeropoulos, George
Almahdali, Sarah
Hadjichristidis, Nikos
Rodionov, Valentin [1 ]
机构：
[1] KAUST, KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia
来源：
MOLECULAR PHARMACEUTICS | 2018年 / 15卷 / 08期
关键词：
poly(vinylidene fluoride); miktoarm star polymer; iodine transfer polymerization; CuAAC; self-assembly; NILE RED; BLOCK; PVDF; COPOLYMERS; POLYMERIZATION; MEMBRANES; POLYMERS; MESHES;
D O I：
10.1021/acs.molpharmaceut.8b00010
中图分类号：
R-3 [医学研究方法]; R3 [基础医学];
学科分类号：
1001 ;
摘要：
A well-defined amphiphilic miktoarm polymer incorporating poly-(vinylidene fluoride) (PVDF), polystyrene (PS), and poly(ethylene glycol) (PEG) blocks was synthesized via a combination of atom-transfer radical polymerization (ATRP), iodine transfer radical polymerization (ITP), and copper-catalyzed azide-alkyne cyclo-addition (CuAAC). Morphology and self-assembly of this star polymer were examined in organic solvents and in water. The aggregates formed in water were found to possess unusual frustrated topology due to immiscibility of PS and PVDF. The polymer was evaluated for transport of small hydrophobic molecules in water.
引用
收藏
页码：3005 / 3009
页数：5
相关论文
共 50 条
  • [21] Self-organization of a 4-miktoarm star block copolymer induced by cylindrical confinement
    Gupta, Supriya
    Chokshi, Paresh
    SOFT MATTER, 2021, 17 (19) : 4929 - 4941
  • [22] Synthesis and self-assembly of Poly(N-octyl benzamide)-μ-poly(ε-caprolactone) miktoarm star copolymers displaying uniform nanofibril morphology
    Huang, Chih-Feng
    Huang, Yi-Shen
    Lai, Kuan-Yu
    POLYMER, 2019, 178
  • [23] Impact of ionic liquid's self-assembly on the crystallization behavior of poly (vinylidene fluoride)
    Bahader, Ali
    Gui Haoguan
    Nawaz, Mohsan
    Bangesh, Masroor
    Bangesh, Fasiha
    Ibrar, M.
    Ding Yunsheng
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 276 : 115 - 119
  • [24] A Novel Photoresponsive Azobenzene-Containing Miktoarm Star Polymer: Self-Assembly and Photoresponse Properties
    Blasco, Eva
    Schmidt, Bernhard V. K. J.
    Barner-Kowollik, Christopher
    Pinol, Milagros
    Oriol, Luis
    MACROMOLECULES, 2014, 47 (11) : 3693 - 3700
  • [25] Synthesis and self-assembly of AB2- and ABC-type miktoarm star polymers
    Khanna, Kunal
    Sharma, Rishi
    Varshney, Sunil K.
    Kakkar, Ashok
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [26] Self-Assembly of Miktoarm Star Polyelectrolytes in Solutions with Various Ionic Strengths
    Bin Li
    Wang, Yong-Lei
    ACS OMEGA, 2022, 7 (24): : 20791 - 20799
  • [27] The impact of intramolecular polydispersity on the self-assembly of ABn miktoarm star copolymers
    Shi, Jiahao
    Huang, Xianbo
    Li, Weihua
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (29) : 20032 - 20041
  • [28] Self-Assembly and pH-Responsiveness of ABC Miktoarm, Star Terpolymers
    Van Butsele, K.
    Fustin, C. A.
    Gohy, J. F.
    Jerome, R.
    Jerome, C.
    LANGMUIR, 2009, 25 (01) : 107 - 111
  • [29] Synthesis of an ABCD 4-Miktoarm Star Quaterpolymer Through a Diels-Alder Click Reaction
    Altintas, Ozcan
    Hizal, Gurkan
    Tunca, Umit
    DESIGNED MONOMERS AND POLYMERS, 2009, 12 (01) : 83 - 98
  • [30] Miktoarm star polymers via cyclodextrin-driven supramolecular self-assembly
    Schmidt, Bernhard V. K. J.
    Hetzer, Martin
    Ritter, Helmut
    Barner-Kowollik, Christopher
    POLYMER CHEMISTRY, 2012, 3 (11) : 3064 - 3067
12345