A Novel Poly(vinylidene fluoride)-Based 4-Miktoarm Star Terpolymer: Synthesis and Self-Assembly

被引：20
|
作者：
Patil, Yogesh
Bilalis, Panayiotis
Polymeropoulos, George
Almahdali, Sarah
Hadjichristidis, Nikos
Rodionov, Valentin [1 ]
机构：
[1] KAUST, KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia
来源：
MOLECULAR PHARMACEUTICS | 2018年 / 15卷 / 08期
关键词：
poly(vinylidene fluoride); miktoarm star polymer; iodine transfer polymerization; CuAAC; self-assembly; NILE RED; BLOCK; PVDF; COPOLYMERS; POLYMERIZATION; MEMBRANES; POLYMERS; MESHES;
D O I：
10.1021/acs.molpharmaceut.8b00010
中图分类号：
R-3 [医学研究方法]; R3 [基础医学];
学科分类号：
1001 ;
摘要：
A well-defined amphiphilic miktoarm polymer incorporating poly-(vinylidene fluoride) (PVDF), polystyrene (PS), and poly(ethylene glycol) (PEG) blocks was synthesized via a combination of atom-transfer radical polymerization (ATRP), iodine transfer radical polymerization (ITP), and copper-catalyzed azide-alkyne cyclo-addition (CuAAC). Morphology and self-assembly of this star polymer were examined in organic solvents and in water. The aggregates formed in water were found to possess unusual frustrated topology due to immiscibility of PS and PVDF. The polymer was evaluated for transport of small hydrophobic molecules in water.
引用
收藏
页码：3005 / 3009
页数：5
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