The coordination chemistry of 4'-(4-tert-butylphenyl)-2,2':6',2''-terpyridine - A solubilising oligopyridine

被引：26

作者：

Constable, EC

Harverson, P

Smith, DR

Whall, L

机构：

[1] Inst. für Anorganische Chemie, CH-4056 Basel

来源：

POLYHEDRON | 1997年 / 16卷 / 20期

关键词：

D O I：

10.1016/S0277-5387(97)00103-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of a solubilised 2,2': 6',2''-terpyridine ligand is described together with the characterisation of an unexpected intermediate. Homoleptic complexes of the solubilised ligand 4'-(4-tert-butylphenyl)-2,2': 6',2''-terpyridine, 1, with cobalt(II), cobalt(III), ruthenium(II), iron(II) and nickel(II) have been prepared. The ligand is slightly electron releasing and solubilises the complexes in organic media. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：3615 / 3623

页数：9

相关论文

共 15 条

[1] A convenient high yield synthesis of 2,2':6',2'':6'',2''':6''',2'''':6'''',2'''''-sexipyridine and helical transition-metal complexes of substituted sexipyridines [J].

Chotalia, R ;

Constable, EC ;

Neuburger, M ;

Smith, DR ;

Zehnder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (22) :4207-4216

[2]

Constable E.C., 1996, Comprehensive Supramolecular Chemistry, V9, P213

[3] THE COORDINATION CHEMISTRY OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE - THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE AND BIS(4'-PHENYL-2,2'-6',2''-TERPYRIDINE)NICKEL(II) CHLORIDE DECAHYDRATE [J].

CONSTABLE, EC ;

LEWIS, J ;

LIPTROT, MC ;

RAITHBY, PR .

INORGANICA CHIMICA ACTA, 1990, 178 (01) :47-54

[4] HIGHER OLIGOPYRIDINES AS A STRUCTURAL MOTIF IN METALLOSUPRAMOLECULAR CHEMISTRY [J].

CONSTABLE, EC .

PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 :67-138

[5] A convergent approach to a solubilised septipyridine [J].

Constable, EC ;

Smith, DR .

TETRAHEDRON, 1997, 53 (05) :1715-1720

[6] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES [J].

CONSTABLE, EC .

ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 :69-121

[7]

CONSTABLE EC, 1992, NEW J CHEM, V16, P855

[8] OLIGOPYRIDINES AS HELICATING LIGANDS [J].

CONSTABLE, EC .

TETRAHEDRON, 1992, 48 (46) :10013-10059

[9] Directional self assembly of a double-helical complex of a solubilised septipyridine [J].

Constable, EC ;

Neuburger, M ;

Smith, DR ;

Zehnder, M .

CHEMICAL COMMUNICATIONS, 1996, (16) :1917-1918

[10] 4-TERT-BUTYLPHENYL SOLUBILIZED OLIGOPYRIDINES [J].

CONSTABLE, EC ;

HARVERSON, P ;

SMITH, DR ;

WHALL, LA .

TETRAHEDRON, 1994, 50 (26) :7799-7806