Effect of Sc and Zr Additions on Recrystallization Behavior and Intergranular Corrosion Resistance of Al-Zn-Mg-Cu Alloys

被引:17
作者
Xia, Peng [1 ,2 ]
Wang, Shuncheng [3 ]
Huang, Huilan [1 ,2 ]
Zhou, Nan [1 ,2 ]
Song, Dongfu [1 ,2 ]
Jia, Yiwang [1 ,2 ]
机构
[1] Guangdong Acad Sci, Inst New Mat, Guangzhou 510650, Peoples R China
[2] Guangdong Acad Sci, Inst New Mat, Guangdong Prov Key Lab Met Toughening Technol & A, Guangzhou 510650, Peoples R China
[3] Guangdong Xingfa Aluminum Co Ltd, Foshan 528137, Peoples R China
基金
中国国家自然科学基金;
关键词
Al-Zn-Mg-Cu alloy; recrystallization; intergranular corrosion; scandium; MECHANICAL-PROPERTIES; ALUMINUM-ALLOY; MICROALLOYING ADDITIONS; LOCALIZED CORROSION; HEAT-TREATMENT; MINOR SC; MICROSTRUCTURE; CRACKING; EVOLUTION; HOMOGENIZATION;
D O I
10.3390/ma14195516
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The recrystallization and intergranular corrosion behaviors impacted by the additions of Sc and Zr in Al-Zn-Mg-Cu alloys are investigated. The stronger effect of coherent Al-3(Sc1-xZrx) phases on pinning dislocation resulted in a lower degree of recrystallization in Al-Zn-Mg-Cu-Sc-Zr alloy, while the subgrain boundaries can escape from the pinning of Al3Zr phases and merge with each other, bringing about a higher degree of recrystallization in Al-Zn-Mg-Cu-Zr alloy. A low degree of recrystallization promotes the precipitation of grain boundary precipitates (GBPs) with a discontinuous distribution, contributing to the high corrosion resistance of Al-Zn-Mg-Cu-Sc-Zr alloy in the central layer. The primary Al-3(Sc1-xZrx) phase promotes recrystallization due to particle-stimulated nucleation (PSN), and acts as the cathode to stimulate an accelerated electrochemical process between the primary Al-3(Sc1-xZrx) particles and GBPs, resulting in a sharp decrease of the corrosion resistance in the surface layer of Al-Zn-Mg-Cu-Sc-Zr alloy.
引用
收藏
页数:19
相关论文
共 51 条
[1]   Analysis of Particle-Stimulated Nucleation (PSN)-Dominated Recrystallization for Hot-Rolled 7050 Aluminum Alloy [J].
Adam, Khaled F. ;
Long, Zhengdong ;
Field, David P. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2017, 48A (04) :2062-2076
[2]  
[Anonymous], 2005, 79982005 GB STAND AD
[3]   Investigating localized corrosion susceptibility arising from Sc containing intermetallic Al3Sc in high strength Al-alloys [J].
Cavanaugh, M. K. ;
Birbilis, N. ;
Buchheit, R. G. ;
Bovard, F. .
SCRIPTA MATERIALIA, 2007, 56 (11) :995-998
[4]   Electrochemical modelling of exfoliation corrosion behaviour of 8090 alloy [J].
Conde, A ;
de Damborenea, J .
ELECTROCHIMICA ACTA, 1998, 43 (08) :849-860
[5]   Effect of Sc and Zr on microstructures and mechanical properties of as-cast Al-Mg-Si-Mn alloys [J].
Dang Jing-zhi ;
Huang Yu-feng ;
Cheng Jun .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2009, 19 (03) :540-544
[6]   Effects of Sc and Zr microalloying additions and aging time at 120 °C on the corrosion behaviour of an Al-Zn-Mg alloy [J].
Deng, Ying ;
Yin, Zhimin ;
Zhao, Kai ;
Duan, Jiaqi ;
Hu, Jian ;
He, Zhenbo .
CORROSION SCIENCE, 2012, 65 :288-298
[7]   Effects of Sc and Zr microalloying additions on the microstructure and mechanical properties of new Al-Zn-Mg alloys [J].
Deng, Ying ;
Yin, Zhimin ;
Zhao, Kai ;
Duan, Jiaqi ;
He, Zhenbo .
JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 530 :71-80
[8]   Three-Stage Homogenization of Al-Zn-Mg-Cu Alloys Containing Trace Zr [J].
Deng, Yun-Lai ;
Zhang, Yun-Ya ;
Wan, Li ;
Zhu, Alf A. ;
Zhang, Xin-Ming .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2013, 44A (06) :2470-2477
[9]   Effect of solidification cooling rate on kinetics of continuous/discontinuous Al3(Sc,Zr) precipitation and the subsequent age-hardening response in cold-rolled AlMgSc(Zr) sheets [J].
Dong, Qingshan ;
Howells, Andrew ;
Lloyd, David J. ;
Gallerneault, Mark ;
Fallah, Vahid .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2020, 772
[10]   Effect of intermetallic phases and recrystallization on the corrosion and fracture behavior of an Al-Zn-Mg-Cu-Zr-Yb-Cr alloy [J].
Fang, H. C. ;
Luo, F. H. ;
Chen, K. H. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2017, 684 :480-490