Towards an Alloy Recycling of Nd-Fe-B Permanent Magnets in a Circular Economy

被引:34
作者
Diehl, Oliver [1 ]
Schoenfeldt, Mario [1 ]
Brouwer, Eva [1 ]
Dirks, Almut [1 ]
Rachut, Karsten [1 ]
Gassmann, Jurgen [1 ]
Gueth, Konrad [1 ]
Buckow, Alexander [1 ]
Gauss, Roland [1 ,2 ]
Stauber, Rudolf [1 ]
Gutfleisch, Oliver [1 ,3 ]
机构
[1] Fraunhofer ISC, Project Grp Mat Recycling & Resource Strategies I, Rodenbacher Chaussee 4, D-63457 Hanau, Germany
[2] EIT RawMat GmbH, Tauentzienstr 11, D-10789 Berlin, Germany
[3] Tech Univ Darmstadt, Mat Sci, Alarich Weiss Str 16, D-64287 Darmstadt, Germany
关键词
Nd-Fe-B; Permanent magnet; Rare earth recycling; Hydrogen decrepitation; Melt-spinning; SINTERED MAGNETS; HOT WORKABILITY; BALANCE PROBLEM; RARE-EARTHS; DYSPROSIUM; RECOVERY; WASTE; HYDROGEN;
D O I
10.1007/s40831-018-0171-7
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Rare earth permanent magnets are an integral part of many electrical and electronic devices as well as numerous other applications, including emerging technologies like wind power, electric vehicles, fully automized industrial machines, and robots. Due to their outstanding properties, magnets based on Nd-Fe-B alloys are often not substitutable by employing less critical material systems. Today, WEEE (Waste Electrical and Electronic Equipment) take-back systems for a variety of products containing Nd-Fe-B magnets are well established. They form an ideal basis for a systematic provision of scrap magnets that can be recycled. Hydrometallurgical approaches that aim at completely dissolving the material to regain elements or oxides are energy and time consuming. Thus, they are costly and come with a large environmental footprint. Recycled rare earth elements and oxides would have to compete with virgin materials from China and can hardly be processed in Europe, due to the lack of respective industries. This paper presents material-to-material recycling approaches, which would maintain the magnet alloys and use them directly for a new magnet production loop. The recycled magnets compete well with those made from primary materials, that is, in terms of magnetic properties as well as in terms of production costs. They excel by far rare earth permanent magnets made from primary materials regarding the environmental footprint. Regarding the shift towards a Green Economy, humanity will consume less fuels in combustion processes but rather exploit functional materials in renewable energy and mobility technologies in the future. This shift fundamentally depends on a circular economy of noble as well as less-noble technology metals.
引用
收藏
页码:163 / 175
页数:13
相关论文
共 28 条
[1]   Evaluating Rare Earth Element Availability: A Case with Revolutionary Demand from Clean Technologies [J].
Alonso, Elisa ;
Sherman, Andrew M. ;
Wallington, Timothy J. ;
Everson, Mark P. ;
Field, Frank R. ;
Roth, Richard ;
Kirchain, Randolph E. .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2012, 46 (06) :3406-3414
[2]  
Bast U., 2014, Recycling von Komponenten und Strategischen Metallen aus Elektrischen Fahrantrieben
[3]   Rare-Earth Economics: The Balance Problem [J].
Binnemans, K. ;
Jones, P. T. ;
Van Acker, K. ;
Blanpain, B. ;
Mishra, B. ;
Apelian, D. .
JOM, 2013, 65 (07) :846-848
[4]   Rare Earths and the Balance Problem [J].
Binnemans K. ;
Jones P.T. .
Journal of Sustainable Metallurgy, 2015, 1 (01) :29-38
[5]   Recycling of rare earths: a critical review [J].
Binnemans, Koen ;
Jones, Peter Tom ;
Blanpain, Bart ;
Van Gerven, Tom ;
Yang, Yongxiang ;
Walton, Allan ;
Buchert, Matthias .
JOURNAL OF CLEANER PRODUCTION, 2013, 51 :1-22
[6]   Dysprosium-free melt-spun permanent magnets [J].
Brown, D. N. ;
Wu, Z. ;
He, F. ;
Miller, D. J. ;
Herchenroeder, J. W. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2014, 26 (06)
[7]   The dependence of magnetic properties and hot workability of rare earth-iron-boride magnets upon composition [J].
Brown, DN ;
Smith, B ;
Ma, BM ;
Campbell, P .
IEEE TRANSACTIONS ON MAGNETICS, 2004, 40 (04) :2895-2897
[8]  
Coey JMD., 1996, RARE EARTH IRON PERM
[9]  
Critical Raw Materials for the EU, 2010, CRIT RAW MAT EU REP
[10]  
Gauss R., 2016, ROHSTOFFWIRTSCHAFT G, P99