Two Coordination Polymers Based on 3-(Carboxymethoxy)benzene-1,2-dioic Acid and N-donor Ancillary Ligands: Synthesis, Crystal structures, and Magnetic Properties

被引：2

作者：

Li, Bo ^{[1
]}

Fan, Hui-Tao ^{[1
]}

Song, Wen-Chao ^{[1
]}

Feng, Chao-Qiang ^{[1
]}

Zang, Shuang-Quan ^{[1
]}

Wang, Li-Ya ^{[1
]}

机构：

[1] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 12-13期

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; Topology; Hydrothermal synthesis; Magnetic properties; SHAPED CARBOXYLATE LIGAND; FRAMEWORKS; MULTICARBOXYLATE; COMPLEXES;

D O I：

10.1002/zaac.201400263

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two coordination polymers were hydrothermally synthesized by reaction of 3-(carboxymethoxy)benzene-1,2-dioic acid (H3L) with divalent zinc or cobalt salts in the presence of ancillary nitrogen ligand. Complex 1 features a three-dimensional metal-organic frame-work with (3,4,4)-connected topology. Complex 2 exhibits a 3D six-connected framework with {4(12).6(3)} topology based on the [Co-4(mu(3)-OH)(2)] tetranuclear clusters as nodes. The magnetic properties of complex 2 were also discussed.

引用

页码：2468 / 2471

页数：4

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