Redox-Assisted Osmium-Promoted C-C Bond Activation of Alkylnitriles

被引：13
作者：
Babon, Juan C. [1 ]
Esteruelas, Miguel A. [1 ]
Fernandez, Israel [2 ]
Lopez, Ana M. [1 ]
Onate, Enrique [1 ]
机构：
[1] Univ Zaragoza, CSIC, Dept Quim Inorgan, ISQCH,Ctr Innovat Quim Avanzada ORFEO CINQA, E-50009 Zaragoza, Spain
[2] Univ Complutense Madrid, Dept Quim Organ 1, Fac Ciencias Quim, Ctr Innovac Quim Avanzada ORFEO CINQA, E-28040 Madrid, Spain
来源：
ORGANOMETALLICS | 2018年 / 37卷 / 13期
关键词：
CARBON-CARBON BONDS; TRANSFER HYDROCYANATION; CLEAVAGE; ACETONITRILE; CHEMISTRY; RHODIUM; NICKEL; INTERCONVERSION; ORGANONITRILES; COMPLEXES;
D O I：
10.1021/acs.organomet.8b00326
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The redox-assisted C(sp)-C(sp(3)) bond activation of alkylnitriles coordinated to osmium(II) dihydride fragments has been performed with an osmium(VI) polyhydride to liberate alkanes and generate dinuclear complexes formed by two osmium(V) polyhydride moieties linked by only one CN bridge. In addition, the bonding situation in these novel dinuclear species has been computationally studied.
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收藏
页码：2014 / 2017
页数：4
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