共 55 条
Selective Glucose-to-Fructose Isomerization over Modified Zirconium UiO-66 in Alcohol Media
被引:49
作者:

de Mello, Matheus Dorneles
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Minnesota, Dept Chem Engn & Mat Sci, 421 Washington Ave SE, Minneapolis, MN 55455 USA Univ Minnesota, Dept Chem Engn & Mat Sci, 421 Washington Ave SE, Minneapolis, MN 55455 USA

论文数: 引用数:
h-index:
机构:
机构:
[1] Univ Minnesota, Dept Chem Engn & Mat Sci, 421 Washington Ave SE, Minneapolis, MN 55455 USA
来源:
关键词:
carbohydrates;
isomerization;
Lewis acids;
metal-organic frameworks;
zeolites;
METAL-ORGANIC FRAMEWORKS;
ACID-CATALYZED CONVERSION;
SN-BETA ZEOLITES;
AQUEOUS-MEDIA;
WATER;
MECHANISM;
DERIVATIVES;
STABILITY;
CHEMISTRY;
ISOMERASE;
D O I:
10.1002/cctc.201800371
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Modulated zirconium metal-organic framework UiO-66 is shown to catalyze the isomerization of D-glucose to D-fructose in alcohol media. Fructose selectivity can change depending on solvent choice. We hypothesize that the difference in selectivity is related to a combined effect of adsorption and solvation effects, which may lead to the high formation of alkylglucosides in depletion of fructose if methanol or ethanol are used. A fructose selectivity of 72% at 82% glucose conversion in 1-PrOH was achieved. The reaction mechanism was investigated using nuclear magnetic resonance spectroscopy. We demonstrate that UiO-66 isomerizes glucose to fructose through an intramolecular C2-C1 hydride transfer. In addition, we show that modulated UiO-66 is a highly active and stable catalyst at the reaction conditions, showing great potential for other sugar reactions.
引用
收藏
页码:2417 / 2423
页数:7
相关论文
共 55 条
[1]
Catalytic Glucose Isomerization by Porous Coordination Polymers with Open Metal Sites
[J].
Akiyama, George
;
Matsuda, Ryotaro
;
Sato, Hiroshi
;
Kitagawa, Susumu
.
CHEMISTRY-AN ASIAN JOURNAL,
2014, 9 (10)
:2772-2777

Akiyama, George
论文数: 0 引用数: 0
h-index: 0
机构:
Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan

Matsuda, Ryotaro
论文数: 0 引用数: 0
h-index: 0
机构:
Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan
RIKEN SPring 8 Ctr, Sayo, Hyogo, Japan Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan

Sato, Hiroshi
论文数: 0 引用数: 0
h-index: 0
机构:
Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan
RIKEN SPring 8 Ctr, Sayo, Hyogo, Japan Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan

Kitagawa, Susumu
论文数: 0 引用数: 0
h-index: 0
机构:
Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan
RIKEN SPring 8 Ctr, Sayo, Hyogo, Japan
Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto, Japan Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Nishikyo Ku, Kyoto, Japan
[2]
A kinetic model for water reactivity (avoiding activities) for hydrolyses in aqueous mixtures - selectivities for solvolyses of 4-substituted benzyl derivatives in alcohol-water mixtures
[J].
Bentley, T. William
;
Koo, In Sun
;
Choi, Hojune
;
Llewellyn, Gareth
.
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY,
2008, 21 (03)
:251-256

Bentley, T. William
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales

Koo, In Sun
论文数: 0 引用数: 0
h-index: 0
机构:
Gyeongsang Natl Univ, Dept Chem Educ, Jinju 660701, South Korea
Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales

Choi, Hojune
论文数: 0 引用数: 0
h-index: 0
机构:
Gyeongsang Natl Univ, Dept Chem Educ, Jinju 660701, South Korea
Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales

Llewellyn, Gareth
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales
[3]
Metalloenzyme-like catalyzed isomerizations of sugars by Lewis acid zeolites
[J].
Bermejo-Deval, Ricardo
;
Assary, Rajeev S.
;
Nikolla, Eranda
;
Moliner, Manuel
;
Roman-Leshkov, Yuriy
;
Hwang, Son-Jong
;
Palsdottir, Arna
;
Silverman, Dorothy
;
Lobo, Raul F.
;
Curtiss, Larry A.
;
Davis, Mark E.
.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,
2012, 109 (25)
:9727-9732

Bermejo-Deval, Ricardo
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA CALTECH, Pasadena, CA 91125 USA

Assary, Rajeev S.
论文数: 0 引用数: 0
h-index: 0
机构:
Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Northwestern Univ, Evanston, IL 60228 USA CALTECH, Pasadena, CA 91125 USA

论文数: 引用数:
h-index:
机构:

Moliner, Manuel
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA
Univ Politecn Valencia, Consejo Super Invest Cient, Inst Tecnol Quim, Valencia 46022, Spain CALTECH, Pasadena, CA 91125 USA

Roman-Leshkov, Yuriy
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA
MIT, Cambridge, MA 02139 USA CALTECH, Pasadena, CA 91125 USA

Hwang, Son-Jong
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA CALTECH, Pasadena, CA 91125 USA

Palsdottir, Arna
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA CALTECH, Pasadena, CA 91125 USA

Silverman, Dorothy
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA CALTECH, Pasadena, CA 91125 USA

Lobo, Raul F.
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Delaware, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA CALTECH, Pasadena, CA 91125 USA

Curtiss, Larry A.
论文数: 0 引用数: 0
h-index: 0
机构:
Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA CALTECH, Pasadena, CA 91125 USA

Davis, Mark E.
论文数: 0 引用数: 0
h-index: 0
机构:
CALTECH, Pasadena, CA 91125 USA CALTECH, Pasadena, CA 91125 USA
[4]
Molecular and industrial aspects of glucose isomerase
[J].
Bhosale, SH
;
Rao, MB
;
Deshpande, VV
.
MICROBIOLOGICAL REVIEWS,
1996, 60 (02)
:280-+

Bhosale, SH
论文数: 0 引用数: 0
h-index: 0
机构:
NATL CHEM LAB, DIV BIOCHEM SCI, PUNE 411008, MAHARASHTRA, INDIA NATL CHEM LAB, DIV BIOCHEM SCI, PUNE 411008, MAHARASHTRA, INDIA

Rao, MB
论文数: 0 引用数: 0
h-index: 0
机构:
NATL CHEM LAB, DIV BIOCHEM SCI, PUNE 411008, MAHARASHTRA, INDIA NATL CHEM LAB, DIV BIOCHEM SCI, PUNE 411008, MAHARASHTRA, INDIA

Deshpande, VV
论文数: 0 引用数: 0
h-index: 0
机构:
NATL CHEM LAB, DIV BIOCHEM SCI, PUNE 411008, MAHARASHTRA, INDIA NATL CHEM LAB, DIV BIOCHEM SCI, PUNE 411008, MAHARASHTRA, INDIA
[5]
Determination of the catalytically active oxidation Lewis acid sites in Sn-beta zeolites, and their optimisation by the combination of theoretical and experimental studies
[J].
Boronat, M
;
Concepción, P
;
Corma, A
;
Renz, M
;
Valencia, S
.
JOURNAL OF CATALYSIS,
2005, 234 (01)
:111-118

Boronat, M
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

Concepción, P
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

Corma, A
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

Renz, M
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

Valencia, S
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[6]
Mechanism of the Meerwein-Ponndorf-Verley-Oppenauer (MPVO) redox equilibrium on Sn- and Zr-beta zeolite catalysts
[J].
Boronat, Mercedes
;
Corma, Avelino
;
Renz, Michael
.
JOURNAL OF PHYSICAL CHEMISTRY B,
2006, 110 (42)
:21168-21174

Boronat, Mercedes
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain

Corma, Avelino
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain

Renz, Michael
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain Univ Politecn Valencia, UPV CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[7]
A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability
[J].
Cavka, Jasmina Hafizovic
;
Jakobsen, Soren
;
Olsbye, Unni
;
Guillou, Nathalie
;
Lamberti, Carlo
;
Bordiga, Silvia
;
Lillerud, Karl Petter
.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
2008, 130 (42)
:13850-13851

Cavka, Jasmina Hafizovic
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Oslo, Dept Chem, N-0315 Oslo, Norway Univ Oslo, Dept Chem, N-0315 Oslo, Norway

Jakobsen, Soren
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Oslo, Dept Chem, N-0315 Oslo, Norway Univ Oslo, Dept Chem, N-0315 Oslo, Norway

论文数: 引用数:
h-index:
机构:

Guillou, Nathalie
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin Yvelines, CNRS, Inst Lavoisier, UMR 8180, F-78035 Versailles, France Univ Oslo, Dept Chem, N-0315 Oslo, Norway

Lamberti, Carlo
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Turin, Dept Chem, IFM & NIS Ctr Excellence, I-10125 Turin, Italy Univ Oslo, Dept Chem, N-0315 Oslo, Norway

论文数: 引用数:
h-index:
机构:

Lillerud, Karl Petter
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Oslo, Dept Chem, N-0315 Oslo, Norway Univ Oslo, Dept Chem, N-0315 Oslo, Norway
[8]
Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal-organic frameworks
[J].
Chen, Jinzhu
;
Li, Kegui
;
Chen, Limin
;
Liu, Ruliang
;
Huang, Xing
;
Ye, Daiqi
.
GREEN CHEMISTRY,
2014, 16 (05)
:2490-2499

Chen, Jinzhu
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China

Li, Kegui
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China

Chen, Limin
论文数: 0 引用数: 0
h-index: 0
机构:
S China Univ Technol, Coll Environm & Energy, Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangzhou 510006, Guangdong, Peoples R China Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China

Liu, Ruliang
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R China Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China

Huang, Xing
论文数: 0 引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
S China Univ Technol, Coll Environm & Energy, Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangzhou 510006, Guangdong, Peoples R China Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China

Ye, Daiqi
论文数: 0 引用数: 0
h-index: 0
机构:
S China Univ Technol, Coll Environm & Energy, Guangdong Prov Key Lab Atmospher Environm & Pollu, Guangzhou 510006, Guangdong, Peoples R China Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
[9]
Catalytic Isomerization of Biomass-Derived Aldoses: A Review
[J].
Delidovich, Irina
;
Palkovits, Regina
.
CHEMSUSCHEM,
2016, 9 (06)
:547-561

Delidovich, Irina
论文数: 0 引用数: 0
h-index: 0
机构:
Rhein Westfal TH Aachen, Chair Heterogeneous Catalysis & Chem Technol, Worringerweg 2, D-52074 Aachen, Germany Rhein Westfal TH Aachen, Chair Heterogeneous Catalysis & Chem Technol, Worringerweg 2, D-52074 Aachen, Germany

Palkovits, Regina
论文数: 0 引用数: 0
h-index: 0
机构:
Rhein Westfal TH Aachen, Chair Heterogeneous Catalysis & Chem Technol, Worringerweg 2, D-52074 Aachen, Germany Rhein Westfal TH Aachen, Chair Heterogeneous Catalysis & Chem Technol, Worringerweg 2, D-52074 Aachen, Germany
[10]
Structure and Dynamics of the Functionalized MOF Type UiO-66(Zr): NMR and Dielectric Relaxation Spectroscopies Coupled with DFT Calculations
[J].
Devautour-Vinot, Sabine
;
Maurin, Guillaume
;
Serre, Christian
;
Horcajada, Patricia
;
da Cunha, Denise Paula
;
Guillerm, Vincent
;
Costa, Elisangela de Souza
;
Taulelle, Francis
;
Martineau, Charlotte
.
CHEMISTRY OF MATERIALS,
2012, 24 (11)
:2168-2177

Devautour-Vinot, Sabine
论文数: 0 引用数: 0
h-index: 0
机构:
ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France
Univ Fed Rio de Janeiro, Inst Chem, BR-21945970 Rio De Janeiro, RJ, Brazil ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Maurin, Guillaume
论文数: 0 引用数: 0
h-index: 0
机构:
ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France
Univ Fed Rio de Janeiro, Inst Chem, BR-21945970 Rio De Janeiro, RJ, Brazil ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Serre, Christian
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Horcajada, Patricia
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

da Cunha, Denise Paula
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Guillerm, Vincent
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Costa, Elisangela de Souza
论文数: 0 引用数: 0
h-index: 0
机构:
ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France
Univ Fed Rio de Janeiro, Inst Chem, BR-21945970 Rio De Janeiro, RJ, Brazil
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Taulelle, Francis
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France

Martineau, Charlotte
论文数: 0 引用数: 0
h-index: 0
机构:
Univ Versailles St Quentin En Yvelines, UMR CNRS 8180, Inst Lavoisier, F-78035 Versailles, France ENSCM, UM2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, F-34095 Montpellier 05, France