Preparation of water-soluble palladium nanocrystals by reverse micelle method: Digestive ripening behavior of mercaptocarboxylic acids as stabilizing agent

被引：16

作者：

Naoe, K. ^{[1
]}

Kataoka, M. ^{[1
]}

Kawagoe, M. ^{[1
]}

机构：

[1] Nara Natl Coll Technol, Dept Chem Engn, Nara 6391080, Japan

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2010年 / 364卷 / 1-3期

关键词：

Reverse micelle; Palladium; Nanoparticle; Stabilizing agent; Water-soluble; GRAM-SCALE SYNTHESIS; GOLD NANOPARTICLES; CITRATE REDUCTION; ZNS NANOPARTICLES; AQUEOUS-PHASE; PD; CATALYSTS; SHAPE; MICROEMULSIONS; CRYSTALLINE;

D O I：

10.1016/j.colsurfa.2010.05.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Worm-like palladium nanoparticles are formed in the reverse micellar organic phase by means of chemical reduction in the water pools of reverse micelles. Water-soluble, spherical Pd nanocrystals are extracted from the worm-like Pd nanoparticles through the digestive ripening behavior of mercaptocarboxylic acids as stabilizing agents. It was found that during the reaction the production of spheres occurs in parallel with the formation of worm-like structure by association of the spheres on increasing the reaction time and the crystallization process occurs even during the extraction. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：116 / 122

页数：7

共 49 条

[1] Forces between surfactant-coated ZnS nanoparticles in dodecane: Effect of water [J].

Alig, Anna R. Godfrey ;

Akbulut, Mustafa ;

Golan, Yuval ;

Israelachvili, Jacob .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (16) :2127-2134

[2] Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 1: The Heck reaction [J].

Alonso, F ;

Beletskaya, IP ;

Yus, M .

TETRAHEDRON, 2005, 61 (50) :11771-11835

[3] Water-soluble palladium(II) catalysts for the alternating co- and terpolymerization of CO and olefins in aqueous phase [J].

Bianchini, C ;

Lee, HM ;

Meli, A ;

Moneti, S ;

Patinec, V ;

Petrucci, G ;

Vizza, F .

MACROMOLECULES, 1999, 32 (12) :3859-3866

[4] SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].

BRUST, M ;

WALKER, M ;

BETHELL, D ;

SCHIFFRIN, DJ ;

WHYMAN, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802

[5] Self-assembled gold nanoparticle thin films with nonmetallic optical and electronic properties [J].

Brust, M ;

Bethell, D ;

Kiely, CJ ;

Schiffrin, DJ .

LANGMUIR, 1998, 14 (19) :5425-5429

[6] Generation of metal oxide nanoparticles in optimised microemulsions [J].

Bumajdad, Ali ;

Eastoe, Julian ;

Zaki, Mohamed I. ;

Heenan, Richard K. ;

Pasupulety, Lata .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 312 (01) :68-75

[7] Architecture of Pd-Au bimetallic nanoparticles in sodium bis(2-ethylhexyl)sulfosuccinate reverse micelles as investigated by X-ray absorption spectroscopy [J].

Chen, Ching-Hsiang ;

Sarma, Loka Subramnanyam ;

Chen, Jiurn-Ming ;

Shih, Shou-Chu ;

Wang, Guo-Rung ;

Liu, Din-Goa ;

Tang, Mau-Tsu ;

Lee, Jyh-Fu ;

Hwang, Bing-Joe .

ACS NANO, 2007, 1 (02) :114-125

[8] Magnetic and Mossbauer spectral study of core/shell structured Fe/Au nanoparticles [J].

Cho, SJ ;

Shahin, AM ;

Long, GJ ;

Davies, JE ;

Liu, K ;

Grandjean, F ;

Kauzlarich, SM .

CHEMISTRY OF MATERIALS, 2006, 18 (04) :960-967

[9] Growth mechanisms and oxidation resistance of gold-coated iron nanoparticles [J].

Cho, SJ ;

Idrobo, JC ;

Olamit, J ;

Liu, K ;

Browning, ND ;

Kauzlarich, SM .

CHEMISTRY OF MATERIALS, 2005, 17 (12) :3181-3186

[10] Aqueous-phase, palladium-catalyzed cross-coupling of aryl bromides under mild conditions, using water-soluble, sterically demanding alkylphosphines [J].

DeVasher, RB ;

Moore, LR ;

Shaughnessy, KH .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (23) :7919-7927

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