A metal-free cathode for organic semiconductor devices

被引:243
作者
Parthasarathy, G [1 ]
Burrows, PE [1 ]
Khalfin, V [1 ]
Kozlov, VG [1 ]
Forrest, SR [1 ]
机构
[1] Princeton Univ, Dept Elect Engn, Ctr Photon & Optoelect Mat POEM, Princeton Mat Inst, Princeton, NJ 08544 USA
关键词
D O I
10.1063/1.121301
中图分类号
O59 [应用物理学];
学科分类号
摘要
We introduce a class of low-reflectivity, high-transparency, nonmetallic cathodes useful for a wide range of electrically active, transparent organic devices. The metal-free cathode employs a thin film of copper phthalocyanine (CuPc) capped with a film of low-power, radio-frequency sputtered indium tin oxide (ITO). The CuPc prevents damage to the underlying organic layers during the ITO sputtering process. We present a model suggesting that damage-induced states at the cathode/organic film interface are responsible for the electron injection properties of the contact. Due to the low contact reflectivity, a non-antireflection-coated, metal-free transparent organic light-emitting device (MF-TOLED) is demonstrated with 85% transmission in the visible, emitting nearly identical amounts of light in the forward and backscattered directions. The MF-TOLED performance is found to be comparable to that of conventional TOLEDs employing a more reflective and absorptive cathode consisting of a semitransparent thin film of Mg:Ag capped with ITO. (C) 1998 American Institute of Physics.
引用
收藏
页码:2138 / 2140
页数:3
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