Two-phase flow pressure drop hysteresis in parallel channels of a proton exchange membrane fuel cell

被引:16
作者
Anderson, Ryan [1 ]
Wilkinson, David P. [1 ]
Bi, Xiaotao [1 ]
Zhang, Lifeng [1 ]
机构
[1] Univ British Columbia, Clean Energy Res Ctr, Dept Biol & Chem Engn, Vancouver, BC V6T 1Z3, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Two-phase flow; Hysteresis; PEM fuel cell; Water management; WATER TRANSPORT; GAS; LIQUID; MALDISTRIBUTION; VISUALIZATION; MANAGEMENT;
D O I
10.1016/j.jpowsour.2009.12.134
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two-phase flow pressure drop hysteresis was studied in a non-operational PEM fuel cell to understand the effect of stoichiometry, GDL characteristics, operating range, and initial conditions (dry vs. flooded) for flow conditions typical of an operating fuel cell. This hysteresis is noted when the air and water flow rates are increased and then decreased along the same path, exhibiting different pressure drops. When starting from dry conditions, the descending pressure drop tended to be higher than the ascending pressure drop at lower simulated current densities. The hysteresis effect was noted for stoichiometries of 1-4 and was eliminated at a stoichiometry of 5. It was found that the hysteresis was greater when water breakthrough occurred at higher simulated current densities, which is a function of GDL properties. The operating range had to reach a critical simulated current density (800 mA cm(-2) in this case) between the ascending and descending approach to create a pressure drop hysteresis zone. The descending step size does not change the size of the hysteresis effect, but a larger step size leads to lower fluctuations in the pressure drop signal. An initially flooded condition also showed hysteresis, but the ascending approach tended to have a higher pressure drop than the descending approach. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:4168 / 4176
页数:9
相关论文
共 27 条
[1]  
Allen J., 2006, ECS Transactions, V3, P1197
[2]  
Barbir F, 2005, SUSTAIN WORLD SER, P1
[3]   Two-phase flow and maldistribution in gas channels of a polymer electrolyte fuel cell [J].
Basu, Suman ;
Li, Jun ;
Wang, Chao-Yang .
JOURNAL OF POWER SOURCES, 2009, 187 (02) :431-443
[4]   Liquid water transport between graphite paper and a solid surface [J].
Bazylak, A. ;
Heinrich, J. ;
Djilali, N. ;
Sinton, D. .
JOURNAL OF POWER SOURCES, 2008, 185 (02) :1147-1153
[5]   Dynamic water transport and droplet emergence in PEMFC gas diffusion layers [J].
Bazylak, Aimy ;
Sinton, David ;
Djilali, Ned .
JOURNAL OF POWER SOURCES, 2008, 176 (01) :240-246
[6]  
BORRELLI J, 2005, P 3 ANN C MICR MIN J
[7]   Measurement of the water transport rate in a proton exchange membrane fuel cell and the influence of the gas diffusion layer [J].
Dai, Wei ;
Wang, Haijiang ;
Yuan, Xiao Zi ;
Martin, Jonathan J. ;
Luo, Zhiping ;
Pan, Mu .
JOURNAL OF POWER SOURCES, 2008, 185 (02) :1267-1271
[8]   Visualization and quantification of cathode channel flooding in PEM fuel cells [J].
Hussaini, Irfan S. ;
Wang, Chao-Yang .
JOURNAL OF POWER SOURCES, 2009, 187 (02) :444-451
[9]   Microscale and macroscale aspects of water management challenges in PEM fuel cells [J].
Kandlikar, Satish G. .
HEAT TRANSFER ENGINEERING, 2008, 29 (07) :575-587
[10]   Drops, slugs, and flooding in polymer electrolyte membrane fuel cells [J].
Kimball, Erin ;
Whitaker, Tamara ;
Kevrekidis, Yannis G. ;
Benziger, Jay B. .
AICHE JOURNAL, 2008, 54 (05) :1313-1332