[Fe2(μ-SR)2(NO)4]0 complexes with R being phenolyl with different substituents in the meta-position: Synthesis, structure, and NO release

被引：14

作者：

Kozub, Galina I. ^{[1
]}

Sanina, Nataliya A. ^{[1
]}

Emel'yanova, Nina S. ^{[1
]}

Utenishev, Andrey N. ^{[1
]}

Kondrat'eva, Tat'yana A. ^{[1
]}

Khrustalev, Vladimir N. ^{[2
]}

Ovanesyan, Nikolay S. ^{[1
]}

Kupchinskaya, Nadezhda E. ^{[3
]}

Aldoshin, Sergey M. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, 1 Acad Semenov Ave, Chernogolovka 142432, Russia

[2] Kurchatov Inst, Natl Res Ctr, Acad Kurchatov Sq 1, Moscow 123182, Russia

[3] Moscow MV Lomonosov State Univ, 1 Leninskie Gory, Moscow 119991, Russia

来源：

INORGANICA CHIMICA ACTA | 2018年 / 480卷

基金：

俄罗斯基础研究基金会;

关键词：

NO donors; Nitrosyl iron complexes; X-ray diffractometry; Mbssbauer spectroscopy; DFT; Amperometry; IRON NITROSYL COMPLEXES; NITRIC-OXIDE; ELECTRONIC-STRUCTURE; NANOPLATFORM; DELIVERY; CRYSTAL; MODELS; DONOR;

D O I：

10.1016/j.ica.2018.05.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of new binuclear tetranitrosyl iron complexes ([Fe-2(SR)(2)(NO)(4)]) have been synthesized, with R m-aminophenyl (1) and m-hydroxyphenyl (2). The structure, physical-chemical properties, and NO release of new complexes in comparison with the formerly studied isostructural analog, the complex with R being m-nitrophenyl ligand, were studied by experimental (X-ray, IR, Mossbauer spectroscopy and amperometry) and theoretical (quantum chemical modeling (DFT)) methods.

引用

页码：132 / 139

页数：8

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