Enhancing sensitivity or resolution of homonuclear correlation experiment for half-integer quadrupolar nuclei

被引：23

作者：

Mali, G ^{[1
]}

Kaucic, V ^{[1
]}

机构：

[1] Natl Inst Chem, SI-1001 Ljubljana, Slovenia

来源：

JOURNAL OF MAGNETIC RESONANCE | 2004年 / 171卷 / 01期

关键词：

MAS NMR; half-integer quadrupolar nuclei; dipolar coupling; double quantum; multiple quantum; CPMG;

D O I：

10.1016/j.jmr.2004.08.003

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

We have recently introduced double-quantum homonuclear correlation NMR experiment for half-integer quadrupolar nuclei in solids, which was based on rotary resonance recoupling [J. Chem. Phys. 120 (2004) 2835]. In this contribution we show on two Na-23 (I = 3/2) containing samples, Na2SO4 and Na2HPO4, that the efficiency of the experiment can be substantially enhanced by adding rotor assisted population transfer (RAPT) and Carr-Purcell-Meiboom-Gill (CPMG) sequences to it. We also present an upgraded two-dimensional experiment, in which double- and six-quantum coherences are correlated during t(1) evolution period, yielding a high-resolution isotropic spectrum along an indirectly detected dimension. The sensitivity of the upgraded experiment is, however, greatly reduced compared to the sensitivity of the original experiment, so that its application is feasible only when RAPT and CPMG can be used as well. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：48 / 56

页数：9

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