Na2MnSiO4 as an attractive high capacity cathode material for sodium-ion battery

被引：73
作者：
Law, Markas [1 ]
Ramar, Vishwanathan [1 ]
Balaya, Palani [1 ]
机构：
[1] Natl Univ Singapore, Dept Mech Engn, Singapore 117575, Singapore
来源：
JOURNAL OF POWER SOURCES | 2017年 / 359卷
关键词：
Sodium manganese silicate; Sodium-ion battery; Cathode material; Energy storage; Polyanion compound; VINYL ETHYLENE CARBONATE; LI-ION; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIAL; INTERCALATION; STABILITY; ADDITIVES; LI2MNSIO4; LIMNPO4; P2-TYPE;
D O I：
10.1016/j.jpowsour.2017.05.069
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Here we report a polyanion-based cathode material for sodium-ion batteries, Na2MnSiO4, registering impressive sodium storage performances with discharge capacity of 210 mAh g(-1) at an average voltage of 3 V at 0.1 C, along with excellent long-term cycling stability (500 cycles at 1 C). Insertion/extraction of similar to 1.5 mol of sodium ion per formula unit of the silicate-based compound is reported and the utilisation of Mn2+ reversible arrow Mn4+ redox couple is also demonstrated by ex-situ XPS. Besides, this study involves a systematic investigation of influence of the electrolyte additive (with different content) on the sodium storage performance of Na2MnSiO4. The electrolyte additive forms an optimum protective passivation film on the electrode surface, successfully reducing manganese dissolution. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：277 / 284
页数：8
相关论文
共 47 条
[1]   Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries [J].
Aurbach, D .
JOURNAL OF POWER SOURCES, 2000, 89 (02) :206-218
[2]   On the use of vinylene carbonate (VC) electrolyte solutions for Li-ion as an additive to batteries [J].
Aurbach, D ;
Gamolsky, K ;
Markovsky, B ;
Gofer, Y ;
Schmidt, M ;
Heider, U .
ELECTROCHIMICA ACTA, 2002, 47 (09) :1423-1439
[3]   A 3.8-V earth-abundant sodium battery electrode [J].
Barpanda, Prabeer ;
Oyama, Gosuke ;
Nishimura, Shin-ichi ;
Chung, Sai-Cheong ;
Yamada, Atsuo .
NATURE COMMUNICATIONS, 2014, 5
[4]   Na2FeP2O7: A Safe Cathode for Rechargeable Sodium-ion Batteries [J].
Barpanda, Prabeer ;
Liu, Guandong ;
Ling, Chris D. ;
Tamaru, Mao ;
Avdeev, Maxim ;
Chung, Sai-Cheong ;
Yamada, Yuki ;
Yamada, Atsuo .
CHEMISTRY OF MATERIALS, 2013, 25 (17) :3480-3487
[5]   Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni [J].
Biesinger, Mark C. ;
Payne, Brad P. ;
Grosvenor, Andrew P. ;
Lau, Leo W. M. ;
Gerson, Andrea R. ;
Smart, Roger St. C. .
APPLIED SURFACE SCIENCE, 2011, 257 (07) :2717-2730
[6]   Studies of the Effect of Varying Vinylene Carbonate (VC) Content in Lithium Ion Cells on Cycling Performance and Cell Impedance [J].
Burns, J. C. ;
Petibon, R. ;
Nelson, K. J. ;
Sinha, N. N. ;
Kassam, Adil ;
Way, B. M. ;
Dahn, J. R. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (10) :A1668-A1674
[7]   Na2MnSiO4 as a positive electrode material for sodium secondary batteries using an ionic liquid electrolyte [J].
Chen, Chih-Yao ;
Matsumoto, Kazuhiko ;
Nohira, Toshiyuki ;
Hagiwara, Rika .
ELECTROCHEMISTRY COMMUNICATIONS, 2014, 45 :63-66
[8]   Thermal stability and phase transformation of electrochemically charged/discharged LiMnPO4 cathode for Li-ion batteries [J].
Choi, Daiwon ;
Xiao, Jie ;
Choi, Young Joon ;
Hardy, John S. ;
Vijayakumar, M. ;
Bhuvaneswari, M. S. ;
Liu, Jun ;
Xu, Wu ;
Wang, Wei ;
Yang, Zhenguo ;
Graff, Gordon L. ;
Zhang, Ji-Guang .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (11) :4560-4566
[9]   Sodium-ion battery cathodes Na2FeP2O7 and Na2MnP2O7: diffusion behaviour for high rate performance [J].
Clark, John M. ;
Barpanda, Prabeer ;
Yamada, Atsuo ;
Islam, M. Saiful .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (30) :11807-11812
[10]   ELECTROCHEMICAL INTERCALATION OF SODIUM IN NAXCOO2 BRONZES [J].
DELMAS, C ;
BRACONNIER, JJ ;
FOUASSIER, C ;
HAGENMULLER, P .
SOLID STATE IONICS, 1981, 3-4 (AUG) :165-169
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