catena-Poly[neodymium(III)-bis[μ-N-(dimorpholinophosphoryl)benzenesulfonamidato]-sodium(I)-bis[μ-N-(dimorpholinophosphoryl)benzenesulfonamidato]]

被引：12

作者：

Shatrava, Iuliia O. ^{[1
]}

Sliva, Tatyana Yu. ^{[1
]}

Ovchynnikov, Vladimir A. ^{[1
]}

Konovalova, Irina S. ^{[2
]}

Amirkhanov, Vladimir M. ^{[1
]}

机构：

[1] Natl Taras Shevchenko Univ, Dept Chem, UA-01033 Kiev, Ukraine

[2] STC Inst Syngle Crystals, UA-61001 Kharkov, Ukraine

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

COMPLEXES; CRYSTAL; SUBSTITUENTS; EXTRACTANTS; COPPER(I); CHEMISTRY; LIGANDS;

D O I：

10.1107/S1600536810008214

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The cubic crystal structure of the title compound, [NaNd(C(14)H(21)N(3)O(5)PS)(4)](n), is composed of one-dimensional polymeric chains propagating in [100], built up from [Nd(C(14)H(21)N(3)O(5)PS)(4)](-) anions and sodium cations functioning as linkers. In the complex anion, the Nd(3+) ion has an eightfold coordination environment formed by the sulfonyl and phosphoryl O atoms of four bidentate chelating N-(dimorpholinophosphoryl)benzenesulfonamidate ligands: the resulting NdO(8) polyhedron can be described as intermediate between dodecahedral and square antiprismatic. The sodium ion adopts an NaO(4) tetrahedral geometry arising from four monodentate benzenesulfonamidate ligands. The resulting crystal structure is unusual because it contains substantial voids (800 angstrom(3) per unit cell), within which there is no evidence of included solvent.

引用

页码：M397 / U584

页数：15

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