Hydrothermal liquefaction of Syrian mesquite (Prosopis farcta): Effects of operating parameters on product yields and characterization by different analysis methods

被引:32
作者
Colak, Utku [1 ]
Durak, Halil [1 ]
Genel, Salih [2 ]
机构
[1] Van Yuzuncu Yil Univ, Vocat Sch Hlth Serv, TR-65080 Van, Turkey
[2] Van Yuzuncu Yil Univ, Educ Fac, TR-65080 Van, Turkey
关键词
Biomass; Bio-fuel; Supercritical fluid; Hydrothermal liquefaction; Prosopis farcta; BIO-OIL PRODUCTION; HOT COMPRESSED WATER; BIOMASS; TEMPERATURE; LIGNIN; CELLULOSE; STRAW;
D O I
10.1016/j.supflu.2018.05.027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, the effect of temperature and catalyst on hydrothermal liquefaction of biomass was investigated. At the end of the experiments, prosopis farcta plant was transformed to solid residue (bio-char) and liquid products (heavy bio-oil, light bio-oil) at temperatures of 250, 300 and 350 degrees C with catalyst (H3BO3, Na2B4O7 center dot 10H(2)O, NaOH) and without catalyst by hydrothermal liquefaction. The liquid and solid products obtained at the end of the experiments were analyzed by GC-MS, FT-IR, 1 H NMR, SEM and elemental analysis methods. The highest liquid product yield was obtained at 350 degrees C with sodium tetraborate catalyst as 35.69%. According to the elemental analysis results, the HHV values of the liquid products range from 19.75 to 29.54 MJ kg(-1) for 300 degrees C and from 18.06 to 30.02 MJ kg(-1) for 350 degrees C. HHV values of all obtained liquid products were found to be higher than raw materials.
引用
收藏
页码:53 / 61
页数:9
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